Acta Cryst. (2007). E63, m80-m82  [ doi:10.1107/S1600536806051403 ]

Tetraphenylphosphonium aquatetracyanonitridorhenate(V) pentahydrate

T. N. Mtshali, W. Purcell and H. G. Visser

Abstract: In the title complex, (C₂₄H₂₀P)₂[Re(CN)₄N(H₂O)]·5H₂O, the Re atom is coordinated by one nitride, one aqua and four cyanide ligands in a distorted octahedral geometry. The Re atom is 0.329 (3) Å from the plane formed by the C atoms of the cyanide ligands.

Online 6 December 2006

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