[1,1′-Bis(diphenyl­phosphino)ferrocene-κ²P,P′]dichloro­platinum(II) chloro­form solvate

The title compound, [PtCl₂{P(C₆H₅)₂Fe(C₅H₄)₂P(C₆H₅)₂}]·CHCl₃, crystallizes with an accompanying chloro­form solvent mol­ecule. The Pt atom shows square-planar coordination.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.022
• wR factor = 0.052
• Data-to-parameter ratio = 20.7

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT062_ALERT_4_C Rescale T(min) & T(max) by .....................       0.94
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          2
            CL1 -PT  -P1  -C31  -142.50  0.30   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          5
            CL1 -PT  -P1  -C11    94.20  0.30   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          8
            CL1 -PT  -P1  -C21   -24.30  0.40   1.555   1.555   1.555   1.555
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          1

Alert level G
ABSTM02_ALERT_3_G  When printed, the submitted absorption T values will be
            replaced by the scaled T values. Since the ratio of scaled T's
            is identical to the ratio of reported T values, the scaling
            does not imply a change to the absorption corrections used in
            the study.
            Ratio of Tmax expected/reported      0.944
            Tmax scaled      0.566 Tmin scaled      0.298

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT-Plus (Bruker, 2004); data reduction: SAINT-Plus and XPREP (Bruker, 2004); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

[1,1'-Bis(diphenylphosphine)ferrocene-κ²P,P']dichloroplatinum(II) chloroform solvate

Crystal data

[PtFeCl2(C17H14P)2]·CHCl3	F(000) = 1832
Mr = 939.71	Dx = 1.879 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 6624 reflections
a = 12.1534 (6) Å	θ = 2.4–28.3°
b = 16.4121 (8) Å	µ = 5.17 mm^−1
c = 16.7053 (8) Å	T = 100 K
β = 94.394 (3)°	Cuboid, yellow
V = 3322.3 (3) Å^3	0.29 × 0.17 × 0.11 mm
Z = 4

Data collection

Bruker X8 APEXII 4K KappaCCD area-detector diffractometer	8237 independent reflections
Graphite monochromator	7233 reflections with I > 2σ(I)
Detector resolution: 512 pixels mm^-1	Rint = 0.040
ω and φ scans	θmax = 28.3°, θmin = 2.1°
Absorption correction: multi-scan (SADABS, Bruker, 2004)	h = −16→16
Tmin = 0.316, Tmax = 0.600	k = −21→21
38208 measured reflections	l = −21→22

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.022	w = 1/[σ^2(Fo^2) + (0.0212P)^2 + 1.9034P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.052	(Δ/σ)max = 0.002
S = 1.06	Δρmax = 0.99 e Å^−3
8237 reflections	Δρmin = −0.77 e Å^−3
397 parameters

Special details

Experimental. The intensity data were collected on a Bruker X8 Apex II 4 K Kappa CCD diffractometer using an exposure time of 5 s/frame. A total of 1119 frames were collected with a frame width of 0.5° covering up to θ = 28.29° with 99.8% completeness accomplished.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt	0.159641 (8)	0.203369 (6)	0.093315 (6)	0.00816 (3)
P1	0.29023 (5)	0.11864 (4)	0.05244 (4)	0.00905 (13)
P2	0.14131 (5)	0.28742 (4)	−0.01479 (4)	0.00977 (13)
Cl1	0.02287 (5)	0.28611 (4)	0.14371 (4)	0.01461 (13)
Cl2	0.14449 (5)	0.12252 (4)	0.20851 (4)	0.01342 (13)
Fe	0.38292 (3)	0.24013 (2)	−0.09034 (2)	0.01047 (8)
C11	0.2319 (2)	0.04027 (15)	−0.01498 (16)	0.0106 (5)
C12	0.1217 (2)	0.04545 (16)	−0.04483 (16)	0.0124 (5)
H12	0.0785	0.091	−0.0316	0.015*
C13	0.0749 (2)	−0.01548 (17)	−0.09367 (17)	0.0163 (6)
H13	0	−0.0113	−0.1142	0.02*
C14	0.1373 (2)	−0.08279 (17)	−0.11275 (16)	0.0151 (6)
H14	0.1046	−0.1249	−0.1456	0.018*
C15	0.2466 (2)	−0.08849 (17)	−0.08396 (17)	0.0161 (6)
H15	0.2894	−0.1341	−0.0979	0.019*
C16	0.2944 (2)	−0.02776 (16)	−0.03465 (16)	0.0135 (5)
H16	0.3693	−0.0323	−0.0143	0.016*
C21	0.3688 (2)	0.06000 (16)	0.13081 (15)	0.0113 (5)
C22	0.3231 (2)	−0.00903 (16)	0.16433 (16)	0.0145 (6)
H22	0.2506	−0.026	0.1465	0.017*
C23	0.3836 (2)	−0.05259 (17)	0.22354 (17)	0.0181 (6)
H23	0.3521	−0.0992	0.2466	0.022*
C24	0.4900 (2)	−0.02856 (17)	0.24946 (17)	0.0180 (6)
H24	0.5309	−0.0586	0.2903	0.022*
C25	0.5365 (2)	0.03903 (17)	0.21583 (17)	0.0161 (6)
H25	0.6097	0.0551	0.2329	0.019*
C26	0.4755 (2)	0.08332 (17)	0.15682 (16)	0.0140 (5)
H26	0.5072	0.13	0.1341	0.017*
C31	0.4004 (2)	0.16553 (16)	0.00395 (16)	0.0106 (5)
C32	0.4597 (2)	0.13331 (17)	−0.06050 (17)	0.0143 (6)
H32	0.4478	0.0819	−0.0858	0.017*
C33	0.5391 (2)	0.19232 (17)	−0.07922 (18)	0.0171 (6)
H33	0.5888	0.1874	−0.1202	0.02*
C34	0.5323 (2)	0.25980 (18)	−0.02677 (18)	0.0182 (6)
H34	0.577	0.3073	−0.0261	0.022*
C35	0.4469 (2)	0.24386 (17)	0.02469 (17)	0.0150 (6)
H35	0.4244	0.2789	0.0656	0.018*
C41	0.2289 (2)	0.28393 (16)	−0.09738 (16)	0.0115 (5)
C42	0.2364 (2)	0.21791 (17)	−0.15316 (16)	0.0140 (5)
H42	0.1954	0.1686	−0.1537	0.017*
C43	0.3163 (2)	0.23967 (18)	−0.20747 (17)	0.0179 (6)
H43	0.338	0.2071	−0.2505	0.022*
C44	0.3577 (2)	0.31805 (18)	−0.18641 (18)	0.0185 (6)
H44	0.4123	0.3468	−0.2129	0.022*
C45	0.3041 (2)	0.34664 (17)	−0.11910 (17)	0.0152 (6)
H45	0.3158	0.3978	−0.0932	0.018*
C51	0.1568 (2)	0.39478 (16)	0.01319 (17)	0.0145 (5)
C52	0.2200 (2)	0.41481 (17)	0.08345 (18)	0.0178 (6)
H52	0.2484	0.373	0.1185	0.021*
C53	0.2415 (3)	0.49624 (18)	0.1022 (2)	0.0247 (7)
H53	0.2837	0.5099	0.1506	0.03*
C54	0.2018 (3)	0.55712 (18)	0.0510 (2)	0.0253 (7)
H54	0.2178	0.6125	0.0636	0.03*
C55	0.1386 (3)	0.53747 (18)	−0.0186 (2)	0.0248 (7)
H55	0.1106	0.5795	−0.0537	0.03*
C56	0.1158 (2)	0.45633 (17)	−0.03763 (19)	0.0202 (6)
H56	0.0721	0.4431	−0.0855	0.024*
C61	0.0074 (2)	0.27138 (16)	−0.07031 (16)	0.0111 (5)
C62	−0.0122 (2)	0.30336 (16)	−0.14761 (17)	0.0154 (6)
H62	0.0436	0.3342	−0.1705	0.018*
C63	−0.1125 (2)	0.29056 (16)	−0.19134 (17)	0.0159 (6)
H63	−0.126	0.3144	−0.243	0.019*
C64	−0.1928 (2)	0.24322 (17)	−0.15999 (17)	0.0161 (6)
H64	−0.2612	0.2341	−0.1901	0.019*
C65	−0.1731 (2)	0.20898 (16)	−0.08414 (17)	0.0146 (6)
H65	−0.2274	0.1753	−0.063	0.018*
C66	−0.0744 (2)	0.22384 (16)	−0.03918 (17)	0.0132 (5)
H66	−0.0624	0.2015	0.0132	0.016*
C	0.9468 (3)	−0.0399 (2)	0.3066 (2)	0.0280 (7)
H0	0.975	0.0119	0.2844	0.034*
Cl3	1.01653 (7)	−0.12216 (5)	0.26529 (5)	0.0341 (2)
Cl4	0.97166 (9)	−0.03814 (6)	0.41147 (6)	0.0448 (3)
Cl5	0.80373 (7)	−0.04613 (5)	0.28071 (5)	0.03336 (19)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt	0.00838 (5)	0.00807 (5)	0.00803 (5)	−0.00026 (4)	0.00061 (3)	−0.00057 (4)
P1	0.0087 (3)	0.0088 (3)	0.0094 (3)	0.0000 (2)	−0.0003 (2)	0.0003 (3)
P2	0.0093 (3)	0.0089 (3)	0.0112 (3)	0.0007 (2)	0.0011 (2)	0.0006 (3)
Cl1	0.0155 (3)	0.0126 (3)	0.0165 (3)	0.0018 (2)	0.0058 (2)	−0.0023 (3)
Cl2	0.0134 (3)	0.0165 (3)	0.0103 (3)	−0.0006 (2)	0.0005 (2)	0.0028 (3)
Fe	0.00952 (18)	0.01083 (18)	0.01120 (19)	−0.00015 (14)	0.00159 (14)	0.00133 (15)
C11	0.0125 (13)	0.0083 (12)	0.0108 (13)	−0.0022 (10)	0.0006 (10)	0.0020 (10)
C12	0.0114 (13)	0.0129 (13)	0.0131 (13)	−0.0005 (10)	0.0023 (10)	0.0011 (11)
C13	0.0143 (14)	0.0198 (14)	0.0145 (14)	−0.0041 (11)	−0.0014 (11)	−0.0005 (12)
C14	0.0217 (15)	0.0132 (13)	0.0107 (13)	−0.0061 (11)	0.0026 (11)	−0.0034 (11)
C15	0.0214 (15)	0.0114 (13)	0.0163 (14)	0.0000 (11)	0.0060 (11)	−0.0019 (11)
C16	0.0123 (13)	0.0130 (13)	0.0149 (14)	0.0006 (10)	−0.0004 (10)	0.0011 (11)
C21	0.0128 (13)	0.0116 (12)	0.0094 (13)	0.0037 (10)	−0.0004 (10)	0.0006 (10)
C22	0.0155 (14)	0.0145 (13)	0.0135 (14)	−0.0007 (10)	0.0014 (10)	−0.0006 (11)
C23	0.0255 (16)	0.0140 (13)	0.0153 (14)	0.0019 (12)	0.0040 (12)	0.0024 (12)
C24	0.0239 (15)	0.0186 (14)	0.0111 (14)	0.0078 (12)	−0.0019 (11)	0.0007 (12)
C25	0.0148 (14)	0.0185 (14)	0.0144 (14)	0.0051 (11)	−0.0025 (11)	−0.0031 (11)
C26	0.0156 (14)	0.0139 (13)	0.0124 (13)	0.0023 (10)	0.0011 (10)	−0.0006 (11)
C31	0.0090 (12)	0.0116 (12)	0.0108 (13)	−0.0001 (10)	−0.0014 (10)	0.0020 (10)
C32	0.0117 (13)	0.0141 (13)	0.0173 (14)	0.0044 (10)	0.0025 (11)	0.0014 (11)
C33	0.0100 (13)	0.0216 (15)	0.0201 (15)	0.0028 (11)	0.0042 (11)	0.0037 (12)
C34	0.0122 (13)	0.0198 (15)	0.0222 (16)	−0.0053 (11)	−0.0023 (11)	−0.0008 (12)
C35	0.0128 (13)	0.0163 (14)	0.0155 (14)	−0.0025 (10)	−0.0018 (11)	−0.0013 (11)
C41	0.0104 (12)	0.0125 (13)	0.0118 (13)	0.0007 (10)	0.0014 (10)	0.0027 (10)
C42	0.0132 (13)	0.0173 (14)	0.0111 (13)	0.0008 (10)	−0.0005 (10)	−0.0011 (11)
C43	0.0180 (15)	0.0239 (15)	0.0122 (14)	0.0027 (12)	0.0030 (11)	−0.0007 (12)
C44	0.0161 (14)	0.0224 (15)	0.0176 (15)	0.0028 (11)	0.0041 (11)	0.0106 (12)
C45	0.0144 (13)	0.0125 (13)	0.0191 (14)	0.0009 (10)	0.0031 (11)	0.0042 (11)
C51	0.0144 (13)	0.0105 (12)	0.0192 (14)	0.0004 (10)	0.0061 (11)	−0.0005 (11)
C52	0.0205 (15)	0.0133 (13)	0.0201 (15)	−0.0035 (11)	0.0037 (12)	0.0000 (12)
C53	0.0278 (17)	0.0213 (16)	0.0255 (17)	−0.0072 (13)	0.0058 (13)	−0.0074 (13)
C54	0.0297 (17)	0.0115 (14)	0.0368 (19)	−0.0027 (12)	0.0159 (14)	−0.0063 (13)
C55	0.0263 (17)	0.0120 (14)	0.0372 (19)	0.0026 (12)	0.0101 (14)	0.0013 (13)
C56	0.0218 (15)	0.0161 (14)	0.0229 (16)	0.0021 (11)	0.0036 (12)	0.0012 (12)
C61	0.0098 (12)	0.0105 (12)	0.0130 (13)	0.0022 (10)	0.0012 (10)	0.0001 (10)
C62	0.0138 (13)	0.0150 (14)	0.0176 (14)	0.0000 (10)	0.0022 (11)	0.0041 (11)
C63	0.0148 (14)	0.0185 (14)	0.0139 (14)	0.0041 (11)	−0.0021 (11)	0.0038 (12)
C64	0.0111 (13)	0.0168 (14)	0.0198 (15)	−0.0003 (10)	−0.0027 (11)	−0.0010 (12)
C65	0.0128 (13)	0.0122 (13)	0.0189 (15)	−0.0014 (10)	0.0018 (11)	0.0043 (11)
C66	0.0147 (13)	0.0110 (12)	0.0140 (14)	0.0020 (10)	0.0015 (11)	0.0022 (11)
C	0.0307 (18)	0.0246 (17)	0.0279 (18)	0.0085 (14)	−0.0029 (14)	−0.0068 (14)
Cl3	0.0370 (5)	0.0345 (5)	0.0301 (4)	0.0150 (4)	−0.0026 (4)	−0.0082 (4)
Cl4	0.0526 (6)	0.0518 (6)	0.0281 (5)	0.0222 (5)	−0.0099 (4)	−0.0113 (4)
Cl5	0.0286 (4)	0.0329 (4)	0.0378 (5)	0.0053 (3)	−0.0021 (4)	−0.0087 (4)

Geometric parameters (Å, º)

Pt—P1	2.2549 (7)	C34—C35	1.422 (4)
Pt—P2	2.2699 (7)	C34—H34	0.95
Pt—Cl1	2.3517 (6)	C35—H35	0.95
Pt—Cl2	2.3562 (6)	C41—C42	1.437 (4)
P1—C31	1.791 (3)	C41—C45	1.441 (4)
P1—C11	1.818 (3)	C42—C43	1.424 (4)
P1—C21	1.833 (3)	C42—H42	0.95
P2—C41	1.807 (3)	C43—C44	1.416 (4)
P2—C51	1.829 (3)	C43—H43	0.95
P2—C61	1.830 (3)	C44—C45	1.421 (4)
C11—C12	1.395 (4)	C44—H44	0.95
C11—C16	1.403 (4)	C45—H45	0.95
C12—C13	1.385 (4)	C51—C56	1.387 (4)
C12—H12	0.95	C51—C52	1.392 (4)
C13—C14	1.390 (4)	C52—C53	1.393 (4)
C13—H13	0.95	C52—H52	0.95
C14—C15	1.381 (4)	C53—C54	1.378 (4)
C14—H14	0.95	C53—H53	0.95
C15—C16	1.391 (4)	C54—C55	1.382 (5)
C15—H15	0.95	C54—H54	0.95
C16—H16	0.95	C55—C56	1.392 (4)
C21—C26	1.389 (4)	C55—H55	0.95
C21—C22	1.398 (4)	C56—H56	0.95
C22—C23	1.385 (4)	C61—C66	1.395 (4)
C22—H22	0.95	C61—C62	1.397 (4)
C23—C24	1.390 (4)	C62—C63	1.388 (4)
C23—H23	0.95	C62—H62	0.95
C24—C25	1.384 (4)	C63—C64	1.381 (4)
C24—H24	0.95	C63—H63	0.95
C25—C26	1.392 (4)	C64—C65	1.390 (4)
C25—H25	0.95	C64—H64	0.95
C26—H26	0.95	C65—C66	1.387 (4)
C31—C35	1.436 (4)	C65—H65	0.95
C31—C32	1.441 (4)	C66—H66	0.95
C32—C33	1.419 (4)	C—Cl4	1.755 (3)
C32—H32	0.95	C—Cl3	1.762 (3)
C33—C34	1.418 (4)	C—Cl5	1.762 (3)
C33—H33	0.95	C—H0	1
P1—Pt—P2	99.34 (2)	C33—C34—C35	108.0 (2)
P1—Pt—Cl1	176.11 (2)	C33—C34—H34	126
P2—Pt—Cl1	84.54 (2)	C35—C34—H34	126
P1—Pt—Cl2	90.05 (2)	C34—C35—C31	108.1 (2)
P2—Pt—Cl2	169.41 (2)	C34—C35—H35	126
Cl1—Pt—Cl2	86.06 (2)	C31—C35—H35	126
C31—P1—C11	107.08 (12)	C42—C41—C45	107.6 (2)
C31—P1—C21	100.47 (12)	C42—C41—P2	126.1 (2)
C11—P1—C21	103.19 (12)	C45—C41—P2	126.3 (2)
C31—P1—Pt	116.10 (9)	C43—C42—C41	107.7 (2)
C11—P1—Pt	111.94 (9)	C43—C42—H42	126.1
C21—P1—Pt	116.60 (9)	C41—C42—H42	126.1
C41—P2—C51	99.83 (12)	C44—C43—C42	108.5 (3)
C41—P2—C61	99.32 (12)	C44—C43—H43	125.8
C51—P2—C61	109.76 (12)	C42—C43—H43	125.8
C41—P2—Pt	124.09 (9)	C43—C44—C45	108.7 (3)
C51—P2—Pt	112.35 (9)	C43—C44—H44	125.7
C61—P2—Pt	110.19 (9)	C45—C44—H44	125.7
C12—C11—C16	119.1 (2)	C44—C45—C41	107.5 (2)
C12—C11—P1	119.8 (2)	C44—C45—H45	126.2
C16—C11—P1	121.03 (19)	C41—C45—H45	126.2
C13—C12—C11	120.4 (3)	C56—C51—C52	119.5 (3)
C13—C12—H12	119.8	C56—C51—P2	121.3 (2)
C11—C12—H12	119.8	C52—C51—P2	118.8 (2)
C12—C13—C14	120.2 (3)	C51—C52—C53	119.9 (3)
C12—C13—H13	119.9	C51—C52—H52	120.1
C14—C13—H13	119.9	C53—C52—H52	120.1
C15—C14—C13	120.0 (3)	C54—C53—C52	120.4 (3)
C15—C14—H14	120	C54—C53—H53	119.8
C13—C14—H14	120	C52—C53—H53	119.8
C14—C15—C16	120.3 (3)	C53—C54—C55	119.9 (3)
C14—C15—H15	119.9	C53—C54—H54	120
C16—C15—H15	119.9	C55—C54—H54	120
C15—C16—C11	120.0 (2)	C54—C55—C56	120.2 (3)
C15—C16—H16	120	C54—C55—H55	119.9
C11—C16—H16	120	C56—C55—H55	119.9
C26—C21—C22	119.2 (2)	C51—C56—C55	120.1 (3)
C26—C21—P1	120.1 (2)	C51—C56—H56	120
C22—C21—P1	120.7 (2)	C55—C56—H56	120
C23—C22—C21	119.9 (3)	C66—C61—C62	118.6 (2)
C23—C22—H22	120	C66—C61—P2	121.5 (2)
C21—C22—H22	120	C62—C61—P2	119.8 (2)
C22—C23—C24	120.4 (3)	C63—C62—C61	120.7 (3)
C22—C23—H23	119.8	C63—C62—H62	119.7
C24—C23—H23	119.8	C61—C62—H62	119.7
C25—C24—C23	120.0 (3)	C64—C63—C62	120.2 (3)
C25—C24—H24	120	C64—C63—H63	119.9
C23—C24—H24	120	C62—C63—H63	119.9
C24—C25—C26	119.6 (3)	C63—C64—C65	119.7 (2)
C24—C25—H25	120.2	C63—C64—H64	120.2
C26—C25—H25	120.2	C65—C64—H64	120.2
C21—C26—C25	120.8 (3)	C66—C65—C64	120.3 (3)
C21—C26—H26	119.6	C66—C65—H65	119.9
C25—C26—H26	119.6	C64—C65—H65	119.9
C35—C31—C32	107.4 (2)	C65—C66—C61	120.5 (3)
C35—C31—P1	124.7 (2)	C65—C66—H66	119.8
C32—C31—P1	127.9 (2)	C61—C66—H66	119.8
C33—C32—C31	107.6 (2)	Cl4—C—Cl3	110.66 (17)
C33—C32—H32	126.2	Cl4—C—Cl5	109.7 (2)
C31—C32—H32	126.2	Cl3—C—Cl5	110.78 (17)
C34—C33—C32	108.9 (3)	Cl4—C—H0	108.5
C34—C33—H33	125.5	Cl3—C—H0	108.5
C32—C33—H33	125.5	Cl5—C—H0	108.5
P2—Pt—P1—C31	41.75 (10)	C21—P1—C31—C32	87.5 (2)
Cl1—Pt—P1—C31	−142.5 (3)	Pt—P1—C31—C32	−145.8 (2)
Cl2—Pt—P1—C31	−143.17 (10)	C35—C31—C32—C33	−1.2 (3)
P2—Pt—P1—C11	−81.62 (9)	P1—C31—C32—C33	179.7 (2)
Cl1—Pt—P1—C11	94.2 (3)	C31—C32—C33—C34	1.3 (3)
Cl2—Pt—P1—C11	93.46 (9)	C32—C33—C34—C35	−0.9 (3)
P2—Pt—P1—C21	159.90 (10)	C33—C34—C35—C31	0.1 (3)
Cl1—Pt—P1—C21	−24.3 (4)	C32—C31—C35—C34	0.6 (3)
Cl2—Pt—P1—C21	−25.02 (10)	P1—C31—C35—C34	179.78 (19)
P1—Pt—P2—C41	−6.90 (11)	C51—P2—C41—C42	−169.0 (2)
Cl1—Pt—P2—C41	173.39 (11)	C61—P2—C41—C42	−56.9 (3)
Cl2—Pt—P2—C41	−159.09 (14)	Pt—P2—C41—C42	65.3 (3)
P1—Pt—P2—C51	−126.98 (10)	C51—P2—C41—C45	11.1 (3)
Cl1—Pt—P2—C51	53.31 (10)	C61—P2—C41—C45	123.2 (2)
Cl2—Pt—P2—C51	80.84 (16)	Pt—P2—C41—C45	−114.5 (2)
P1—Pt—P2—C61	110.30 (9)	C45—C41—C42—C43	0.8 (3)
Cl1—Pt—P2—C61	−69.42 (9)	P2—C41—C42—C43	−179.0 (2)
Cl2—Pt—P2—C61	−41.89 (17)	C41—C42—C43—C44	−0.3 (3)
C31—P1—C11—C12	−118.6 (2)	C42—C43—C44—C45	−0.3 (3)
C21—P1—C11—C12	135.9 (2)	C43—C44—C45—C41	0.8 (3)
Pt—P1—C11—C12	9.8 (2)	C42—C41—C45—C44	−1.0 (3)
C31—P1—C11—C16	64.5 (2)	P2—C41—C45—C44	178.9 (2)
C21—P1—C11—C16	−41.0 (2)	C41—P2—C51—C56	67.1 (3)
Pt—P1—C11—C16	−167.16 (19)	C61—P2—C51—C56	−36.6 (3)
C16—C11—C12—C13	−0.4 (4)	Pt—P2—C51—C56	−159.6 (2)
P1—C11—C12—C13	−177.4 (2)	C41—P2—C51—C52	−106.8 (2)
C11—C12—C13—C14	0.6 (4)	C61—P2—C51—C52	149.5 (2)
C12—C13—C14—C15	−1.0 (4)	Pt—P2—C51—C52	26.5 (3)
C13—C14—C15—C16	1.1 (4)	C56—C51—C52—C53	0.1 (4)
C14—C15—C16—C11	−1.0 (4)	P2—C51—C52—C53	174.0 (2)
C12—C11—C16—C15	0.6 (4)	C51—C52—C53—C54	−0.9 (5)
P1—C11—C16—C15	177.6 (2)	C52—C53—C54—C55	1.2 (5)
C31—P1—C21—C26	23.5 (2)	C53—C54—C55—C56	−0.6 (5)
C11—P1—C21—C26	134.0 (2)	C52—C51—C56—C55	0.5 (4)
Pt—P1—C21—C26	−102.9 (2)	P2—C51—C56—C55	−173.3 (2)
C31—P1—C21—C22	−155.7 (2)	C54—C55—C56—C51	−0.2 (5)
C11—P1—C21—C22	−45.2 (3)	C41—P2—C61—C66	141.7 (2)
Pt—P1—C21—C22	77.9 (2)	C51—P2—C61—C66	−114.2 (2)
C26—C21—C22—C23	0.9 (4)	Pt—P2—C61—C66	10.0 (2)
P1—C21—C22—C23	−179.9 (2)	C41—P2—C61—C62	−34.6 (2)
C21—C22—C23—C24	−0.6 (4)	C51—P2—C61—C62	69.5 (2)
C22—C23—C24—C25	−0.3 (4)	Pt—P2—C61—C62	−166.30 (19)
C23—C24—C25—C26	0.9 (4)	C66—C61—C62—C63	2.3 (4)
C22—C21—C26—C25	−0.3 (4)	P2—C61—C62—C63	178.8 (2)
P1—C21—C26—C25	−179.5 (2)	C61—C62—C63—C64	−2.5 (4)
C24—C25—C26—C21	−0.6 (4)	C62—C63—C64—C65	0.5 (4)
C11—P1—C31—C35	161.1 (2)	C63—C64—C65—C66	1.6 (4)
C21—P1—C31—C35	−91.5 (2)	C64—C65—C66—C61	−1.8 (4)
Pt—P1—C31—C35	35.2 (2)	C62—C61—C66—C65	−0.2 (4)
C11—P1—C31—C32	−19.9 (3)	P2—C61—C66—C65	−176.6 (2)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C66—H66···Cl1	0.95	2.72	3.350 (3)	124