Acta Cryst. (2007). E63, m75-m77  [ doi:10.1107/S1600536806051427 ]

catena-Poly[[[bis(1,10-phenanthroline)cadmium(II)]--naphthalene-2,6-dicarboxylato] monohydrate]

L. Ye, J.-W. Ye, K.-Q. Ye and Y. Wang

Abstract: The title cadmium coordination polymer, {[Cd(C₁₂H₆O₄)(C₁₂H₈N₂)₂]·H₂O}_n, has been synthesized and characterized by single-crystal X-ray diffraction. Each Cd^II cation is coordinated by two carboxylate O atoms belonging to two NDC anions (NDC is naphthalene-2,6-dicarboxylate) and four N atoms from two phen ligands (phen is 1,10-phenanthroline). Each NDC anion bridges two Cd^II cations through the two terminal carboxylate groups in a monodentate fashion to form a zigzag polymeric chain and there are - interactions between adjacent chains. The title coordination polymer exhibits an extended three-dimensional network feature based on interchain hydrogen bonding and and - stacking interactions.

Online 6 December 2006

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