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Acta Cryst. (2007). E63, m484-m486  [ doi:10.1107/S1600536807000992 ]

Bis[6,6'-dimethoxy-2,2'-(ethane-1,2-diyldiiminodimethylene)diphenolato-[kappa]2N,N',O,O']cerium(IV)

Y.-F. Liu, H.-T. Xia, D.-Q. Wang and S.-P. Yang

Abstract: In the title compound, [Ce(C18H22N2O4)2], the Ce atoms are eight-coordinate and there are three independent molecules in the asymmetric unit. Two tetradentate N,N'-(2-hydroxy-3-methoxybenzyl)ethane-1,2-diamine ligands are coordinated to each CeIV atom. The molecules are linked into a chain by three C-H...O hydrogen bonds. Neighbouring chains are connected by van der Waals forces, resulting in a three-dimensional network.

Online 17 January 2007


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