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Acta Cryst. (2007). E63, i30-i32 [ doi:10.1107/S1600536806056194 ]
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-cyano-dicopper(II)molybdate(IV) monohydrate]Abstract: The structure of the title compound, Cu2[Mo(CN)8]·4H2O, contains MoIV ions in a distorted square-antiprismatic geometry (site symmetry 1) linked through CN ligands to four Jahn-Teller-distorted octahedral CuII ions (site symmetry 2) and four trigonal-bipyramidal CuII ions (site symmetry 1).
Online 10 January 2007
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