(IUCr) Crystallography Journals Online

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Acta Cryst. (2007). E63, m482-m483 [ doi:10.1107/S1600536807000979 ]

catena-Poly[[[acetonitrilebis[-bis(diphenylphosphino)methane-²P:P']dicopper(I)]--(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)tungstate(IV)]--(1,2-dicyanoethylene-1,2-dithiolato)] diethyl ether disolvate acetonitrile solvate]

W.-W. Fu and Z.-N. Chen

Abstract: The reaction between [Cu₂( [mu] -bis(diphenylphosphino)methane)₂(MeCN)₂](ClO₄)₂ and (Bu₄N)₂[W(cis-1,2-dicyanoethylene-1,2-dithiolate)₃] gave the title compound, {[Cu₂W(C₄N₂S₂)₃(C₂H₃N)(C₂₅H₂₂P₂)₂]·2C₄H₁₀O·C₂H₃N}_n. Due to the binding between a Cu atom of the binuclear copper unit [Cu₂{bis(diphenylphosphino)methane}₂(MeCN)]²⁺ and the N atoms of the buliding block [W(cis-1,2-dicyano-ethylene-1,2-dithiolate)₃]^2-, a one-dimensional zigzag chain structure is formed.

Online 17 January 2007

catena-Poly[[[acetonitrilebis[-bis(diphenylphosphino)methane-2P:P']dicopper(I)]--(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)tungstate(IV)]--(1,2-dicyanoethylene-1,2-dithiolato)] diethyl ether disolvate acetonitrile solvate]

W.-W. Fu and Z.-N. Chen

catena-Poly[[[acetonitrilebis[-bis(diphenylphosphino)methane-²P:P']dicopper(I)]--(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)tungstate(IV)]--(1,2-dicyanoethylene-1,2-dithiolato)] diethyl ether disolvate acetonitrile solvate]