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Acta Cryst. (2007). E63, m593-m595  [ doi:10.1107/S1600536807003157 ]

cis-Bis(2,2'-bipyridine)difluorochromium(III) perchlorate

Y. Yamaguchi-Terasaki, T. Fujihara, A. Nagasawa and S. Kaizaki

Abstract: In the title compound, cis-[CrF2(C10H8N2)2]ClO4, the CrIII ion is coordinated by the four N atoms [Cr-N = 2.0480 (14)-2.0842 (14) Å] from two 2,2'-bipyridine ligands and two F- ions [Cr-F = 1.8409 (10) and 1.8541 (10) Å] in a distorted octahedral arrangement. The crystal packing is stabilized by [pi]-[pi] interactions and weak intermolecular C-H...F and C-H...O hydrogen bonds.

Online 26 January 2007


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