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Acta Cryst. (2007). E63, m569-m571  [ doi:10.1107/S1600536807002292 ]

Di-[mu]-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-[kappa]3N,O,O'}nickel(II)) methanol solvate

K. Van Hecke, P. Nockemann, K. Binnemans and L. Van Meervelt

Abstract: The title compound, [Ni2Cl2(C9H10NO2)2]·CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each NiII atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.

Online 24 January 2007


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