Acta Cryst. (2007). E63, m576-m578  [ doi:10.1107/S1600536807002462 ]

Chlorido(6-diphenylphosphino-2-pyridonato-²P,N)(6-diphenylphosphino-2-hydroxypyridine-²P,N)hydridoiridium(III) chloroform 1.896-solvate

T. Miyabayashi, T. Hara, T. Yamagata and K. Mashima

Abstract: The title complex, [Ir(C₁₇H₁₃NOP)ClH(C₁₇H₁₄NOP)]·1.896CHCl₃, contains hydride, chloride, 6-diphenylphosphino-2-hydroxypyridine (pyphosH) and 6-diphenylphosphino-2-pyridonate (pyphos) ligands coordinated to an Ir^III metal centre to give a distorted octahedral coordination geometry. The two P and two N atoms of the pyphosH and pyphos ligands lie with a cis coordination in the equatorial plane. An intramolecular O-HO hydrogen bond is observed between the pyphosH and pyphos ligands.

Online 24 January 2007

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