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Acta Cryst. (2007). E63, o446-o447  [ doi:10.1107/S1600536806054857 ]

(Z)-Ethyl 2-[2-(3-bromophenyl)hydrazono]-4-chloro-3-oxobutanoate

G. Alpaslan, Ö. Özdamar, M. Odabasoglu, N. Ocak Ískeleli and A. Erdönmez

Abstract: There are two crystallographically independent molecules in the asymmetric unit of the title compound, C12H12ClBrN2O3. The molecules adopt a keto-hydrazo tautomeric form, stabilized by an intramolecular hydrogen bond. The aromatic ring and aliphatic chain have a trans configuration about the N-N bond. The molecules pack via weak intermolecular C-H...O hydrogen bonds which, together with an intramolecular N-H...O bond, form an S(6)[R22(14)]S(6) motif.

Online 6 January 2007


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