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Acta Cryst. (2007). E63, m625-m627 [ doi:10.1107/S1600536807003777 ]
-thiocyanato-
4S:S-argentate(I)]-di-
-thiocyanato-
4S:N-bis[diamminecopper(II)]-di-
-thiocyanato-
4N:S]Abstract: The title compound, [CuIIAgI(SCN)3(NH3)4]n, consists of two single chains of CuN6 Jahn-Teller-distorted octahedra and AgS4 tetrahedra connected by thiocyanate groups. Both metal atoms are located on twofold rotation axes. The two single chains are connected, forming a double chain along the a axis. Adjacent double chains are linked into a three-dimensional network by N-H
N hydrogen bonds.
Online 31 January 2007
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