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Acta Cryst. (2007). E63, m625-m627  [ doi:10.1107/S1600536807003777 ]

catena-Poly[[di-[mu]-thiocyanato-[kappa]4S:S-argentate(I)]-di-[mu]-thiocyanato-[kappa]4S:N-bis[diamminecopper(II)]-di-[mu]-thiocyanato-[kappa]4N:S]

D.-S. Liu, S.-F. Liu, Y.-P. Xu, G.-S. Huang and X.-F. Li

Abstract: The title compound, [CuIIAgI(SCN)3(NH3)4]n, consists of two single chains of CuN6 Jahn-Teller-distorted octahedra and AgS4 tetrahedra connected by thiocyanate groups. Both metal atoms are located on twofold rotation axes. The two single chains are connected, forming a double chain along the a axis. Adjacent double chains are linked into a three-dimensional network by N-H...N hydrogen bonds.

Online 31 January 2007


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