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Acta Cryst. (2007). E63, m743-m745  [ doi:10.1107/S1600536807006423 ]

Aquabis(dichloroacetato-[kappa]O)bis(nicotinamide-[kappa]N)copper(II)

J. Moncol, J. Maroszová, M. Múdra, T. Lis and M. Koman

Abstract: In the title compound, [Cu(Cl2CHCO2)2(C6H6N2O)2(H2O)], both the CuII atom and the O atom of the coordinated water molecule lie on a crystallographic twofold rotation axis. The CuII atom is coordinated by O atoms from two monodentate chloroacetate anions, pyridine N atoms from two monodentate nicotinamide ligands and by the water molecule, forming a tetragonal-pyramidal coordination polyhedron. The complexes are linked by O-H...O, N-H...O and C-H...O hydrogen bonds into a three-dimensional network.

Online 14 February 2007


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