Acta Cryst. (2007). E63, m680-m682  [ doi:10.1107/S1600536807005259 ]

cis-Dichloro(di-tert-butylphosphine-P)(triphenylphosphine-P)platinum(II) tetrahydrofuran hemisolvate

J. Chojnacki, A. Robaszkiewicz, E. Matern, E. Baum and J. Pikies

Abstract: The title compound, [PtCl₂(C₈H₁₉P)(C₁₈H₁₅P)]·0.5C₄H₈O, was obtained in the reaction of bis(triphenylphosphine)platinum(II) chloride with 1,1,3,3-tetra-tert-butyl-2-trimethylsilyltriphosphine. The ³¹P{¹H} NMR spectrum of the reaction mixture shows the formation of the title compound together with a significant amount of triphenylphosphine and 1,1,3,3-tetra-tert-butyltriphosphine.

Online 7 February 2007

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