Acta Cryst. (2007). E63, m719-m721  [ doi:10.1107/S1600536807006101 ]

{N,N-Bis[(diphenylphosphino)methyl]aniline}tetracarbonylmolybdenum(0)

N. M. Sanchez Ballester, M. R. J. Elsegood, M. B. Smith and G. M. Brown

Abstract: The title compound, [Mo(CO)₄{Ph₂PCH₂N(Ph)CH₂PPh₂}] or [Mo(C₃₂H₂₉NP₂)(CO)₄], is a tetracarbonylmolybdenum(0) complex of a chelating ditertiary phosphine with a P-C-N-C-P backbone. The geometry at the Mo centre is octahedral, while both diphenylphosphino centres coordinate in a cis fashion.

Online 14 February 2007

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