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Acta Cryst. (2007). E63, m842-m844 [ doi:10.1107/S1600536807004679 ]
Abstract: The reaction between [Cu2(![[mu]](/logos/entities/mu_rmgif.gif)
-dppm)2(MeCN)2](ClO4)2 and (Bu4N)2[Mo(mnt)3], where dppm is bis(diphenylphosphino)methane and mnt is cis-1,2-dicyanoethylene-1,2-dithiolate, gave the title compound, catena-Poly[[[acetonitrilebis[-bis(diphenylphosphino)methane-![[kappa]](/logos/entities/kappa_rmgif.gif)
2P:P']dicopper(I)]--(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)molybdenum(IV)]--(1,2-dicyanoethylene-1,2-dithiolato)] diethyl ether disolvate acetonitrile solvate]. The binding between a Cu atom of the binuclear copper unit [Cu2(-dppm)2(MeCN)]2+ and two N atoms of the building block [Mo(mnt)3]2- results in the formation of a one-dimensional zigzag chain structure.
Online 23 February 2007
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