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Acta Cryst. (2007). E63, m698-m700  [ doi:10.1107/S1600536807005454 ]

Aquabis(3-pyridylacrylato)-[kappa]2O,O';[kappa]O-bis(3-pyridylmethanol-[kappa]N)copper(II)

J. Moncol, P. Segla, J. Jasková, A. Fischer and M. Melník

Abstract: In the title complex, [Cu(C8H6NO2)2(C6H7NO)2(H2O)], the Cu2+ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of 3-pyridylmethanol ligands and one water O atom. O-H...O and O-H...N hydrogen bonds result in the formation of a two-dimensional layer structure.

Online 9 February 2007


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