Acta Cryst. (2007). E63, m795-m797  [ doi:10.1107/S1600536807007349 ]

-Trithiocyanurato-⁴N¹,S²:N³,S⁴-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-³N,N',N'')zinc(II)] perchlorate monohydrate

Z. Trávnícek, J. Marek and S. Cermáková

Abstract: In the title compound, [Zn₂(C₃N₃S₃)(C₉H₂₃N₃)₂]ClO₄·H₂O, the dinuclear Zn^II metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms, and an S and an N atom of ttc. The crystal structure is stabilized by O-HO, O-HS, C-HS and C-HO interactions connecting the cations, the ClO₄^- anions and the water molecules.

Online 21 February 2007

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