Acta Cryst. (2007). E63, m918-m920  [ doi:10.1107/S1600536807008665 ]

Di--benzenethiolato--chlorido-bis{hydrido[(S)-(-)-2,2'-bis(di-p-tolylphosphanyl)-1,1'-binaphthyl]iridium(III)} chloride 1,2-dichloroethane disolvate

T. Yamagata, K. Hoshida, A. Iseki and K. Tani

Abstract: The cation of the title compound, [Ir₂ClH₂(C₆H₅S)₂(C₄₈H₄₀P₂)₂]Cl·2C₂H₄Cl₂, exists as a bridged bifacial octahedral dinuclear iridium structure with C₂ symmetry (Cl lies on the rotation axis). The coordination environment of the Ir atom can be described as highly distorted octahedral with two P atoms, two bridging phenyl thiolato S atoms, a bridging chloride ligand, and a terminal hydride ligand.

Online 28 February 2007

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