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Acta Cryst. (2007). E63, m664-m666  [ doi:10.1107/S1600536807004588 ]

[mu]-2,2'-Biphenolato-[kappa]2O:O'-[mu]-oxido-[kappa]2O:O-bis[bis(hexafluoroacetylacetonato-[kappa]2O,O')titanium(IV)]

A. Kuhn, A. Muller and J. Conradie

Abstract: The coordination of [Ti(hfaa)2Cl2] (hfaa = hexafluoroacetylacetonate) with the hydroxyl-containing bidentate ligand 2,2'-biphenol yielded the title compound, [{Ti(hfaa)2}2([mu]-2,2'-biphenolato)([mu]-oxo)] or [Ti2(C5HF6O2)4(C12H8O2)O]. The molecule has crystallographic twofold rotation symmetry. The biphenolate ligand bridges the two Ti atoms.

Online 7 February 2007


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