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Acta Cryst. (2007). E63, m845-m846  [ doi:10.1107/S1600536807006290 ]

Dichloro(ethanol-[kappa]O){(E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazonato-[kappa]3N,N',S}indium(III)

Y.-J. Fan, L. Wang, J.-P. Ma and Z.-X. Sun

Abstract: Reaction of indium(III) chloride with (E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazide afforded the title complex, [In(C8H9N4S)Cl2(C2H5OH)]. The ligand is in the enol form coordinating to the InIII atom through one S atom and two N atoms. The InIII atom is further coordinated by two Cl atoms and an ethanol molecule to complete a distorted octahedral coordination geometry.

Online 23 February 2007


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