Acta Cryst. (2007). E63, m865-m867  [ doi:10.1107/S1600536807008057 ]

Tetraphenylphosphonium [N-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamido(4-)-⁴S,N,N',N'']oxorhenate(V)

J. Le Gal, É. Benoist, M. Gressier, F. Bélanger-Gariépy and A. L. Beauchamp

Abstract: The title compound, (C₂₄H₂₀P)[Re(C₁₀H₉N₃O₂S)O], contains well separated square-pyramidal [OReL]^- complex anions (L is the deprotonated N-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamide ligand) and tetrahedral [(C₆H₅)₄P]⁺ cations. In the anion, the Re=O bond is oriented along the apical direction and the four basal sites are occupied by one S- and three N-atom donors of the tetradentate L^4- ligand.

Online 28 February 2007

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