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The title compound, (C24H20P)[Re(C10H9N3O2S)O], contains well separated square-pyramidal [OReL] complex anions (L is the deprotonated N-(2-amino­phen­yl)-2-(mercaptomethyl­carbonyl­amino)­ethanamide ligand) and tetra­hedral [(C6H5)4P]+ cations. In the anion, the Re=O bond is oriented along the apical direction and the four basal sites are occupied by one S– and three N-atom donors of the tetra­dentate L4− ligand.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807008057/kj2046sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807008057/kj2046Isup2.hkl
Contains datablock I

CCDC reference: 640400

Key indicators

  • Single-crystal X-ray study
  • T = 100 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.026
  • wR factor = 0.068
  • Data-to-parameter ratio = 15.4

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT141_ALERT_4_C su on a - Axis Small or Missing (x 100000) ..... 10 Ang. PLAT143_ALERT_4_C su on c - Axis Small or Missing (x 100000) ..... 10 Ang. PLAT180_ALERT_3_C Check Cell Rounding: # of Values Ending with 0 = 4
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 4 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1999); cell refinement: SMART; data reduction: SAINT (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: UdMX (Maris, 2004).

Tetraphenylphosphonium [N-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamide(4-)- κ4S,N,N',N'']oxorhenate(V) top
Crystal data top
(C24H20P)[Re(C10H9N3O3S)O]F(000) = 1536
Mr = 776.83Dx = 1.692 Mg m3
Monoclinic, P21/cCu Kα radiation, λ = 1.54178 Å
Hall symbol: -P 2ybcCell parameters from 6535 reflections
a = 10.4122 (1) Åθ = 3.0–72.8°
b = 29.0410 (3) ŵ = 9.25 mm1
c = 10.1031 (1) ÅT = 100 K
β = 93.151 (1)°Platelet, red
V = 3050.36 (5) Å30.30 × 0.18 × 0.09 mm
Z = 4
Data collection top
Bruker SMART 2K/PLATFORM
diffractometer
5969 independent reflections
Radiation source: sealed tube5387 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.030
Detector resolution: 5.5 pixels mm-1θmax = 72.8°, θmin = 3.0°
ω scansh = 1212
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
k = 3535
Tmin = 0.168, Tmax = 0.435l = 1112
24723 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.026Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.068H-atom parameters constrained
S = 1.02 w = 1/[σ2(Fo2) + (0.0478P)2]
where P = (Fo2 + 2Fc2)/3
5969 reflections(Δ/σ)max = 0.004
388 parametersΔρmax = 1.41 e Å3
0 restraintsΔρmin = 0.89 e Å3
Special details top

Experimental. X-ray crystallographic data for I were collected from a single-crystal sample, which was mounted on a loop fiber. Data were collected using a Bruker Platform diffractometer, equipped with a Bruker SMART 2 K Charged-Coupled Device (CCD) Area Detector using the program SMART and normal focus sealed tube source graphite monochromated Cu—Kα radiation. The crystal-to-detector distance was 4.908 cm, and the data collection was carried out in 512 x 512 pixel mode, utilizing 4 x 4 pixel binning. The initial unit-cell parameters were determined by a least-squares fit of the angular setting of strong reflections, collected by a 9.0 degree scan in 30 frames over four different parts of the reciprocal space (120 frames total). One complete sphere of data was collected, to better than 0.8 Å resolution. Upon completion of the data collection, the first 101 frames were recollected in order to improve the decay correction analysis.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Re10.277826 (11)0.688832 (4)0.454100 (12)0.01197 (6)
O10.32518 (19)0.73379 (7)0.5539 (2)0.0181 (4)
N10.1883 (2)0.71171 (8)0.2905 (2)0.0153 (5)
H10.23130.72080.22260.018*
C20.0548 (3)0.71298 (10)0.2861 (3)0.0146 (6)
C30.0008 (3)0.69101 (9)0.3933 (3)0.0145 (6)
N40.0943 (2)0.67063 (8)0.4801 (2)0.0140 (5)
C50.0701 (3)0.63638 (10)0.5699 (3)0.0153 (6)
O50.0353 (2)0.62403 (8)0.6025 (2)0.0216 (5)
C60.1942 (3)0.61412 (10)0.6260 (3)0.0168 (6)
H6A0.21130.62360.71940.020*
H6B0.18570.58020.62350.020*
N70.3003 (2)0.62846 (8)0.5469 (2)0.0143 (5)
C80.4043 (3)0.59999 (10)0.5414 (3)0.0169 (6)
O80.4203 (2)0.56480 (7)0.6073 (2)0.0223 (5)
C90.4999 (3)0.61441 (10)0.4413 (3)0.0189 (6)
H9A0.51810.58770.38450.023*
H9B0.58150.62340.48930.023*
S100.44396 (7)0.66223 (2)0.33569 (7)0.01836 (15)
C210.0248 (3)0.73356 (10)0.1872 (3)0.0182 (6)
H210.01140.74780.11320.022*
C220.1574 (3)0.73317 (10)0.1977 (3)0.0205 (6)
H220.21150.74710.13020.025*
C230.2118 (3)0.71271 (10)0.3055 (3)0.0196 (6)
H230.30240.71330.31210.024*
C240.1341 (3)0.69137 (10)0.4042 (3)0.0177 (6)
H240.17120.67730.47780.021*
P10.82419 (7)0.59714 (2)0.93069 (7)0.01364 (14)
C310.9842 (3)0.61925 (10)0.9555 (3)0.0158 (6)
C321.0173 (3)0.66199 (10)0.9056 (3)0.0173 (6)
H320.95530.67990.85600.021*
C331.1424 (3)0.67829 (11)0.9290 (3)0.0218 (7)
H331.16630.70730.89420.026*
C341.2316 (3)0.65237 (12)1.0027 (3)0.0240 (7)
H341.31620.66401.01990.029*
C351.1990 (3)0.60941 (12)1.0520 (3)0.0246 (7)
H351.26120.59161.10150.030*
C361.0748 (3)0.59288 (11)1.0281 (3)0.0212 (6)
H361.05170.56361.06130.025*
C410.7852 (3)0.57077 (10)1.0852 (3)0.0165 (6)
C420.8174 (3)0.59344 (11)1.2039 (3)0.0188 (6)
H420.85980.62241.20350.023*
C430.7869 (3)0.57336 (11)1.3225 (3)0.0230 (7)
H430.80840.58861.40400.028*
C440.7252 (3)0.53107 (12)1.3226 (3)0.0255 (7)
H440.70450.51751.40430.031*
C450.6937 (3)0.50841 (12)1.2051 (3)0.0261 (7)
H450.65150.47941.20610.031*
C460.7237 (3)0.52806 (11)1.0857 (3)0.0217 (6)
H460.70250.51261.00460.026*
C510.7098 (3)0.64136 (10)0.8854 (3)0.0163 (6)
C520.6418 (3)0.66335 (10)0.9830 (3)0.0181 (6)
H520.65700.65531.07370.022*
C530.5521 (3)0.69692 (11)0.9464 (4)0.0219 (7)
H530.50750.71261.01240.026*
C540.5274 (3)0.70775 (10)0.8136 (3)0.0214 (7)
H540.46310.72980.78890.026*
C550.5962 (3)0.68642 (10)0.7163 (4)0.0205 (7)
H550.58030.69440.62570.025*
C560.6883 (3)0.65333 (10)0.7520 (3)0.0193 (6)
H560.73630.63900.68620.023*
C610.8148 (3)0.55292 (10)0.8063 (3)0.0154 (6)
C620.6937 (3)0.53921 (10)0.7537 (3)0.0177 (6)
H620.61910.55620.77360.021*
C630.6829 (3)0.50080 (11)0.6723 (3)0.0219 (6)
H630.60110.49140.63540.026*
C640.7925 (3)0.47612 (11)0.6451 (3)0.0251 (7)
H640.78480.44900.59280.030*
C650.9132 (3)0.49051 (11)0.6932 (3)0.0253 (7)
H650.98780.47410.67060.030*
C660.9248 (3)0.52902 (10)0.7746 (3)0.0190 (6)
H661.00720.53900.80820.023*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Re10.00914 (8)0.01189 (8)0.01495 (9)0.00008 (4)0.00121 (5)0.00005 (4)
O10.0148 (10)0.0157 (10)0.0235 (11)0.0009 (8)0.0009 (8)0.0013 (8)
N10.0139 (11)0.0189 (12)0.0133 (12)0.0004 (9)0.0029 (9)0.0026 (9)
C20.0150 (13)0.0133 (13)0.0155 (15)0.0007 (10)0.0000 (11)0.0017 (10)
C30.0112 (13)0.0153 (14)0.0169 (15)0.0006 (10)0.0002 (11)0.0032 (10)
N40.0093 (11)0.0161 (12)0.0167 (13)0.0003 (9)0.0015 (9)0.0019 (9)
C50.0143 (13)0.0175 (14)0.0145 (14)0.0013 (11)0.0042 (11)0.0020 (11)
O50.0162 (10)0.0256 (12)0.0235 (12)0.0019 (9)0.0049 (9)0.0064 (9)
C60.0180 (14)0.0152 (14)0.0176 (15)0.0006 (11)0.0030 (12)0.0043 (11)
N70.0130 (11)0.0141 (12)0.0156 (12)0.0011 (9)0.0005 (9)0.0013 (9)
C80.0153 (13)0.0146 (14)0.0207 (16)0.0007 (11)0.0003 (12)0.0031 (11)
O80.0185 (10)0.0182 (11)0.0300 (13)0.0042 (8)0.0000 (9)0.0041 (9)
C90.0120 (13)0.0173 (14)0.0274 (17)0.0039 (11)0.0022 (12)0.0004 (12)
S100.0128 (3)0.0206 (4)0.0224 (4)0.0019 (3)0.0065 (3)0.0015 (3)
C210.0213 (15)0.0180 (15)0.0153 (15)0.0011 (11)0.0012 (12)0.0002 (11)
C220.0197 (15)0.0187 (15)0.0224 (16)0.0035 (12)0.0047 (12)0.0005 (12)
C230.0124 (13)0.0185 (15)0.0276 (17)0.0018 (11)0.0016 (12)0.0022 (12)
C240.0143 (15)0.0187 (15)0.0201 (16)0.0004 (11)0.0016 (12)0.0017 (11)
P10.0108 (3)0.0138 (3)0.0164 (4)0.0001 (3)0.0009 (3)0.0002 (3)
C310.0135 (13)0.0179 (14)0.0160 (15)0.0000 (11)0.0003 (11)0.0016 (11)
C320.0172 (14)0.0176 (14)0.0172 (15)0.0003 (11)0.0023 (11)0.0036 (11)
C330.0230 (16)0.0171 (15)0.0258 (17)0.0051 (12)0.0054 (13)0.0029 (12)
C340.0150 (14)0.0300 (18)0.0268 (18)0.0060 (12)0.0007 (12)0.0056 (14)
C350.0189 (14)0.0285 (18)0.0257 (18)0.0015 (13)0.0055 (13)0.0022 (13)
C360.0185 (14)0.0210 (16)0.0238 (17)0.0013 (12)0.0000 (12)0.0044 (12)
C410.0125 (13)0.0189 (15)0.0182 (15)0.0008 (11)0.0015 (11)0.0018 (11)
C420.0158 (13)0.0189 (15)0.0219 (16)0.0032 (11)0.0026 (12)0.0004 (12)
C430.0189 (15)0.0320 (18)0.0183 (16)0.0092 (13)0.0015 (12)0.0004 (13)
C440.0229 (16)0.0313 (18)0.0230 (17)0.0076 (13)0.0084 (13)0.0106 (13)
C450.0258 (16)0.0229 (17)0.0300 (19)0.0009 (13)0.0061 (14)0.0076 (13)
C460.0232 (15)0.0205 (16)0.0214 (16)0.0022 (12)0.0027 (12)0.0012 (12)
C510.0117 (13)0.0131 (14)0.0238 (16)0.0003 (10)0.0004 (11)0.0002 (11)
C520.0150 (13)0.0186 (15)0.0204 (16)0.0010 (11)0.0006 (12)0.0020 (11)
C530.0132 (14)0.0203 (15)0.0327 (19)0.0006 (11)0.0045 (13)0.0052 (13)
C540.0122 (13)0.0152 (15)0.0364 (19)0.0001 (11)0.0030 (13)0.0001 (13)
C550.0187 (15)0.0171 (15)0.0252 (18)0.0008 (11)0.0023 (13)0.0022 (12)
C560.0161 (14)0.0184 (15)0.0235 (16)0.0005 (11)0.0017 (12)0.0008 (12)
C610.0168 (13)0.0144 (14)0.0150 (14)0.0009 (11)0.0016 (11)0.0011 (11)
C620.0159 (13)0.0181 (15)0.0192 (16)0.0013 (11)0.0028 (12)0.0010 (11)
C630.0229 (15)0.0228 (16)0.0196 (16)0.0016 (12)0.0040 (12)0.0006 (12)
C640.0341 (18)0.0197 (16)0.0213 (17)0.0030 (13)0.0003 (14)0.0041 (12)
C650.0253 (16)0.0254 (17)0.0255 (18)0.0113 (13)0.0020 (14)0.0001 (13)
C660.0140 (13)0.0211 (15)0.0220 (16)0.0006 (11)0.0025 (12)0.0028 (12)
Geometric parameters (Å, º) top
Re1—O11.706 (2)C33—H330.95
Re1—N11.968 (2)C34—C351.392 (5)
Re1—N71.996 (2)C34—H340.95
Re1—N42.013 (2)C35—C361.388 (4)
Re1—S102.2908 (7)C35—H350.95
N1—C21.389 (4)C36—H360.95
N1—H10.88C41—C421.393 (4)
C2—C211.398 (4)C41—C461.396 (4)
C2—C31.408 (4)C42—C431.385 (4)
C3—C241.399 (4)C42—H420.95
C3—N41.416 (4)C43—C441.386 (5)
N4—C51.379 (4)C43—H430.95
C5—O51.216 (3)C44—C451.381 (5)
C5—C61.526 (4)C44—H440.95
C6—N71.460 (4)C45—C461.385 (4)
C6—H6a0.99C45—H450.95
C6—H6b0.99C46—H460.95
N7—C81.366 (4)C51—C561.398 (4)
C8—O81.226 (4)C51—C521.399 (4)
C8—C91.517 (4)C52—C531.386 (4)
C9—S101.827 (3)C52—H520.95
C9—H9a0.99C53—C541.388 (5)
C9—H9b0.99C53—H530.95
C21—C221.390 (4)C54—C551.394 (5)
C21—H210.95C54—H540.95
C22—C231.389 (4)C55—C561.391 (4)
C22—H220.95C55—H550.95
C23—C241.394 (4)C56—H560.95
C23—H230.95C61—C661.392 (4)
C24—H240.95C61—C621.399 (4)
P1—C311.790 (3)C62—C631.387 (4)
P1—C511.793 (3)C62—H620.95
P1—C611.796 (3)C63—C641.388 (5)
P1—C411.805 (3)C63—H630.95
C31—C321.390 (4)C64—C651.387 (5)
C31—C361.393 (4)C64—H640.95
C32—C331.394 (4)C65—C661.389 (4)
C32—H320.95C65—H650.95
C33—C341.381 (5)C66—H660.95
O1—Re1—N1110.27 (10)C33—C32—H32120.3
O1—Re1—N4111.66 (10)C34—C33—C32120.1 (3)
N1—Re1—N477.85 (10)C34—C33—H33120
O1—Re1—N7111.82 (10)C32—C33—H33120
N1—Re1—N7136.81 (10)C33—C34—C35120.7 (3)
N4—Re1—N778.22 (10)C33—C34—H34119.6
O1—Re1—S10111.40 (7)C35—C34—H34119.6
N1—Re1—S1090.66 (7)C36—C35—C34119.4 (3)
N7—Re1—S1082.91 (7)C36—C35—H35120.3
N4—Re1—S10136.79 (7)C34—C35—H35120.3
C2—N1—Re1117.55 (19)C35—C36—C31120.0 (3)
C2—N1—H1121.2C35—C36—H36120
Re1—N1—H1121.2C31—C36—H36120
N1—C2—C21126.0 (3)C42—C41—C46120.4 (3)
N1—C2—C3114.6 (3)C42—C41—P1119.3 (2)
C21—C2—C3119.4 (3)C46—C41—P1120.3 (2)
C24—C3—C2120.6 (3)C43—C42—C41119.4 (3)
C24—C3—N4128.1 (3)C43—C42—H42120.3
C2—C3—N4111.3 (3)C41—C42—H42120.3
C5—N4—C3124.2 (2)C42—C43—C44120.1 (3)
C5—N4—Re1119.01 (19)C42—C43—H43120
C3—N4—Re1116.46 (19)C44—C43—H43120
O5—C5—N4126.3 (3)C45—C44—C43120.7 (3)
O5—C5—C6122.2 (3)C45—C44—H44119.7
N4—C5—C6111.6 (2)C43—C44—H44119.7
N7—C6—C5109.1 (2)C44—C45—C46119.8 (3)
N7—C6—H6A109.9C44—C45—H45120.1
C5—C6—H6A109.9C46—C45—H45120.1
N7—C6—H6B109.9C45—C46—C41119.6 (3)
C5—C6—H6B109.9C45—C46—H46120.2
H6A—C6—H6B108.3C41—C46—H46120.2
C8—N7—C6118.4 (2)C56—C51—C52120.4 (3)
C8—N7—Re1125.8 (2)C56—C51—P1119.5 (2)
C6—N7—Re1115.78 (18)C52—C51—P1120.1 (2)
O8—C8—N7124.5 (3)C53—C52—C51119.5 (3)
O8—C8—C9121.2 (3)C53—C52—H52120.2
N7—C8—C9114.3 (3)C51—C52—H52120.2
C8—C9—S10113.6 (2)C52—C53—C54120.3 (3)
C8—C9—H9A108.9C52—C53—H53119.9
S10—C9—H9A108.9C54—C53—H53119.9
C8—C9—H9B108.9C53—C54—C55120.4 (3)
S10—C9—H9B108.9C53—C54—H54119.8
H9A—C9—H9B107.7C55—C54—H54119.8
C9—S10—Re1100.2 (1)C56—C55—C54119.9 (3)
C22—C21—C2119.7 (3)C56—C55—H55120.1
C22—C21—H21120.2C54—C55—H55120.1
C2—C21—H21120.2C55—C56—C51119.6 (3)
C23—C22—C21120.8 (3)C55—C56—H56120.2
C23—C22—H22119.6C51—C56—H56120.2
C21—C22—H22119.6C66—C61—C62120.4 (3)
C22—C23—C24120.4 (3)C66—C61—P1120.3 (2)
C22—C23—H23119.8C62—C61—P1118.9 (2)
C24—C23—H23119.8C63—C62—C61119.8 (3)
C23—C24—C3119.1 (3)C63—C62—H62120.1
C23—C24—H24120.5C61—C62—H62120.1
C3—C24—H24120.5C62—C63—C64119.5 (3)
C31—P1—C51112.25 (14)C62—C63—H63120.3
C31—P1—C61111.68 (14)C64—C63—H63120.3
C51—P1—C61108.89 (14)C65—C64—C63121.0 (3)
C31—P1—C41106.43 (14)C65—C64—H64119.5
C51—P1—C41110.27 (14)C63—C64—H64119.5
C61—P1—C41107.20 (14)C64—C65—C66119.8 (3)
C32—C31—C36120.5 (3)C64—C65—H65120.1
C32—C31—P1121.1 (2)C66—C65—H65120.1
C36—C31—P1118.4 (2)C65—C66—C61119.5 (3)
C31—C32—C33119.3 (3)C65—C66—H66120.3
C31—C32—H32120.3C61—C66—H66120.3
O1—Re1—N1—C296.5 (2)C51—P1—C31—C3218.2 (3)
N7—Re1—N1—C270.0 (3)C61—P1—C31—C32104.4 (3)
N4—Re1—N1—C212.3 (2)C41—P1—C31—C32138.9 (2)
S10—Re1—N1—C2150.3 (2)C51—P1—C31—C36160.9 (2)
Re1—N1—C2—C21170.9 (2)C61—P1—C31—C3676.5 (3)
Re1—N1—C2—C39.2 (3)C41—P1—C31—C3640.2 (3)
N1—C2—C3—C24177.3 (3)C36—C31—C32—C330.1 (5)
C21—C2—C3—C242.7 (4)P1—C31—C32—C33178.9 (2)
N1—C2—C3—N42.3 (4)C31—C32—C33—C340.9 (5)
C21—C2—C3—N4177.6 (2)C32—C33—C34—C351.4 (5)
C24—C3—N4—C519.8 (5)C33—C34—C35—C360.9 (5)
C2—C3—N4—C5160.5 (3)C34—C35—C36—C310.0 (5)
C24—C3—N4—Re1167.0 (2)C32—C31—C36—C350.6 (5)
C2—C3—N4—Re112.6 (3)P1—C31—C36—C35178.5 (3)
O1—Re1—N4—C592.9 (2)C31—P1—C41—C4243.5 (3)
N1—Re1—N4—C5159.9 (2)C51—P1—C41—C4278.5 (3)
N7—Re1—N4—C516.1 (2)C61—P1—C41—C42163.1 (2)
S10—Re1—N4—C582.1 (2)C31—P1—C41—C46136.4 (2)
O1—Re1—N4—C393.6 (2)C51—P1—C41—C46101.7 (3)
N1—Re1—N4—C313.6 (2)C61—P1—C41—C4616.7 (3)
N7—Re1—N4—C3157.4 (2)C46—C41—C42—C430.5 (4)
S10—Re1—N4—C391.4 (2)P1—C41—C42—C43179.7 (2)
C3—N4—C5—O512.4 (5)C41—C42—C43—C440.1 (4)
Re1—N4—C5—O5174.7 (2)C42—C43—C44—C450.1 (5)
C3—N4—C5—C6167.0 (3)C43—C44—C45—C460.1 (5)
Re1—N4—C5—C65.9 (3)C44—C45—C46—C410.3 (5)
O5—C5—C6—N7166.9 (3)C42—C41—C46—C450.5 (5)
N4—C5—C6—N712.5 (3)P1—C41—C46—C45179.6 (2)
C5—C6—N7—C8153.3 (2)C31—P1—C51—C5687.0 (3)
C5—C6—N7—Re126.1 (3)C61—P1—C51—C5637.2 (3)
O1—Re1—N7—C895.0 (2)C41—P1—C51—C56154.5 (2)
N1—Re1—N7—C898.6 (3)C31—P1—C51—C5293.6 (3)
N4—Re1—N7—C8156.1 (3)C61—P1—C51—C52142.2 (2)
S10—Re1—N7—C815.2 (2)C41—P1—C51—C5224.9 (3)
O1—Re1—N7—C685.6 (2)C56—C51—C52—C530.5 (4)
N1—Re1—N7—C680.8 (2)P1—C51—C52—C53178.9 (2)
N4—Re1—N7—C623.21 (19)C51—C52—C53—C541.8 (5)
S10—Re1—N7—C6164.1 (2)C52—C53—C54—C552.7 (5)
C6—N7—C8—O86.5 (4)C53—C54—C55—C561.4 (5)
Re1—N7—C8—O8174.1 (2)C54—C55—C56—C510.8 (4)
C6—N7—C8—C9171.4 (2)C52—C51—C56—C551.8 (4)
Re1—N7—C8—C97.9 (4)P1—C51—C56—C55177.6 (2)
O8—C8—C9—S10170.4 (2)C31—P1—C61—C6621.6 (3)
N7—C8—C9—S107.6 (3)C51—P1—C61—C66146.1 (2)
C8—C9—S10—Re115.8 (2)C41—P1—C61—C6694.6 (3)
O1—Re1—S10—C996.23 (13)C31—P1—C61—C62165.9 (2)
N1—Re1—S10—C9151.65 (12)C51—P1—C61—C6241.4 (3)
N7—Re1—S10—C914.48 (12)C41—P1—C61—C6277.9 (3)
N4—Re1—S10—C978.82 (15)C66—C61—C62—C631.8 (4)
N1—C2—C21—C22178.4 (3)P1—C61—C62—C63170.6 (2)
C3—C2—C21—C221.7 (4)C61—C62—C63—C640.6 (5)
C2—C21—C22—C230.2 (5)C62—C63—C64—C653.0 (5)
C21—C22—C23—C241.2 (5)C63—C64—C65—C662.8 (5)
C22—C23—C24—C30.3 (4)C64—C65—C66—C610.4 (5)
C2—C3—C24—C231.7 (4)C62—C61—C66—C651.9 (4)
N4—C3—C24—C23178.6 (3)P1—C61—C66—C65170.4 (2)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H1···O1i0.882.403.259 (3)164
Symmetry code: (i) x, y+3/2, z1/2.
 

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