Acta Cryst. (2007). E63, m868-m869 [ doi:10.1107/S1600536807008070 ]
Abstract: The title compound, (C24H20P)[Re(C11H11N3O2S)O], is the [(C6H5)4P]+ salt of a square-pyramidal [ReOL]- complex anion [L is the deprotonated 2-(mercaptomethylcarbonylamino)-N-(2-methylaminophenyl)ethanamide ligand], in which the Re=O bond is apical and the tetradentate (N-N-N-S)4- ligand fills the four basal sites. The presence of a methyl group on the terminal N-atom donor induces a small displacement of the coordinated S atom.
Online 28 February 2007
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