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Acta Cryst. (2007). E63, m692-m694  [ doi:10.1107/S1600536807005363 ]

Bis(1H-benzimidazole-[kappa]N3)bis(naphthalene-2-acetato-[kappa]2O,O')cadmium(II) monohydrate

J.-G. Duan, J.-W. Liu and S. Wu

Abstract: The CdII ion of the title mononuclear complex, [Cd(C12H9O2)2(C7H6N2)2]·H2O, lies on a crystallographic twofold rotation axis and is in a distorted trigonal prismatic coordination enivironment, involving four carboxylate O atoms from two chelating naphthaleneacetate ligands and two N atoms from two benzimidazole ligands. In the crystal structure, intermolecular N-H...O hydrogen bonds and [pi]-[pi] stacking interactions give rise to a one-dimensional chain structure. The solvent water molecule also lies on a crystallographic twofold rotation axis.

Online 7 February 2007


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