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Acta Cryst. (2007). E63, m737-m739  [ doi:10.1107/S1600536807005739 ]

catena-Poly[[(2,2'-bipyridine-[kappa]2N,N')manganese(II)]-[mu]-3,5-dinitro-2-oxidobenzoato-[kappa]4O,O':O',O2]

W.-D. Song, X.-X. Guo and G. Rong-Fa

Abstract: In the title complex, [Mn(C7H2N2O7)(C10H8N2)]n, the MnII atom has a distorted octahedral coordination geometry, defined by two N atoms from the 2,2'-bipyridine ligand and four O atoms from two 3,5-dinitrosalicylate dianions. One carboxylate O atom acts as a bridge between adjacent metal centres to form a one-dimensional chain. The Mn...Mn distance is 4.315 (6) Å. The crystal packing is stabilized by intermolecular C-H...O hydrogen interactions.

Online 14 February 2007


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