addenda and errata\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

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ISSN: 2056-9890

Bis­{(Z)-N′-(2,4-di­chloro­benzyl­­idene)-2-hy­droxy­benzohydrazide-κ2N′,O}bis­(pyridine-κN)cobalt(II). Corrigendum11

CROSSMARK_Color_square_no_text.svg

aDepartment of Chemistry, Lanzhou University, Lanzhou 730000, People's Republic of China, bDepartment of Chemistry, Fuyang Normal College, Fuyang Anhui 236041, People's Republic of China, and cInstitute of Functional Biomolecules, State Key Laboratory of Pharmaceutical Biotechnology, Nanjing University, Nanjing 210093, People's Republic of China
*Correspondence e-mail: liuws@lzu.edu.cn, hailiang_zhu@163.com

(Received 17 November 2006; accepted 8 February 2007; online 14 February 2007)

In the original paper by Qiu, Yang, Liu & Zhu [Acta Cryst. (2006), E62, m1320–m1231], the H atoms attached to N1 and N3 are positioned incorrectly. These have been deleted and the structure rerefined. The correct name of the structure is bis­(2,4-dichloro­benzaldehyde 2-hydroxy­benzoyl­hydrazonato-κ2N,O)bis­(pyridine-κN)cobalt(II). The scheme, figure, Crystal data, Refinement and hydrogen-bond table are corrected.

[Scheme 1]
[Figure 1]
Figure 1
The structure of (I)[link], showing 30% probability displacement ellipsoids and the atom-numbering scheme. The dashed lines indicate hydrogen bonds.

2. Experimental

2.1.1. Crystal data
  • [Co(C14H9Cl2N2O2)2(C5H5N)2]

  • Mr = 833.39

  • Monoclinic, P 21 /n

  • a = 13.1832 (5) Å

  • b = 12.2799 (5) Å

  • c = 23.2108 (10) Å

  • β = 97.934 (2)°

  • V = 3721.6 (3) Å3

  • Z = 4

  • Mo Kα radiation

  • μ = 0.80 mm−1

  • T = 298 (2) K

  • 0.36 × 0.26 × 0.14 mm

2.1.3. Refinement
  • R[F2 > 2σ(F2)] = 0.043

  • wR(F2) = 0.092

  • S = 1.02

  • 7675 reflections

  • 486 parameters

  • H atoms treated by a mixture of independent and constrained refinement

  • Δρmax = 0.34 e Å−3

  • Δρmin = −0.37 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
O1—H1⋯N1 0.80 (3) 1.87 (3) 2.566 (3) 144 (3)
O3—H16⋯N3 0.84 (4) 1.83 (4) 2.564 (3) 146 (3)

Supporting information


Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.

bis(2,4-dichlorobenzaldehyde 2-hydroxybenzoylhydrazonato-κ2N,O)bis(pyridine-κN)cobalt(II) top
Crystal data top
[Ni(C14H9Cl2N2O2)2(C5H5N)2]F(000) = 1700
Mr = 833.39Dx = 1.487 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 6285 reflections
a = 13.1832 (5) Åθ = 4.2–26°
b = 12.2799 (5) ŵ = 0.80 mm1
c = 23.2108 (10) ÅT = 298 K
β = 97.934 (2)°Block, red
V = 3721.6 (3) Å30.36 × 0.26 × 0.14 mm
Z = 4
Data collection top
Bruker SMART APEX area-detector
diffractometer
7675 independent reflections
Radiation source: fine-focus sealed tube5595 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.033
ω scansθmax = 26.5°, θmin = 1.8°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1616
Tmin = 0.778, Tmax = 0.889k = 1515
21284 measured reflectionsl = 2919
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.043Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.092H atoms treated by a mixture of independent and constrained refinement
S = 1.02 w = 1/[σ2(Fo2) + (0.031P)2 + 1.5838P]
where P = (Fo2 + 2Fc2)/3
7675 reflections(Δ/σ)max = 0.001
486 parametersΔρmax = 0.34 e Å3
0 restraintsΔρmin = 0.37 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C11.15574 (17)0.11735 (19)0.12753 (10)0.0378 (6)
C21.22602 (19)0.1207 (2)0.17894 (11)0.0470 (7)
C31.3216 (2)0.0729 (3)0.17980 (13)0.0601 (8)
H3A1.36920.07760.21320.072*
C41.3469 (2)0.0190 (3)0.13222 (14)0.0663 (9)
H41.41080.01400.13390.080*
C51.2782 (2)0.0132 (3)0.08185 (13)0.0635 (8)
H51.29510.02370.04950.076*
C61.1844 (2)0.0627 (2)0.07994 (12)0.0499 (7)
H61.13870.05960.04570.060*
C71.05404 (17)0.17037 (18)0.12285 (11)0.0355 (6)
C80.90674 (19)0.3037 (2)0.20930 (11)0.0451 (6)
H80.95820.31180.24070.054*
C90.80515 (19)0.3460 (2)0.21520 (10)0.0423 (6)
C100.7922 (2)0.4400 (2)0.24674 (11)0.0467 (6)
C110.6970 (2)0.4766 (2)0.25651 (12)0.0541 (7)
H110.69040.54010.27750.065*
C120.6124 (2)0.4172 (3)0.23463 (12)0.0547 (7)
C130.6206 (2)0.3239 (2)0.20292 (13)0.0565 (7)
H130.56250.28450.18830.068*
C140.7169 (2)0.2894 (2)0.19313 (11)0.0490 (7)
H140.72260.22680.17120.059*
C150.68982 (18)0.53726 (19)0.09960 (11)0.0390 (6)
C160.7077 (2)0.6370 (2)0.12921 (11)0.0440 (6)
C170.6250 (2)0.6985 (2)0.14198 (13)0.0593 (8)
H170.63680.76300.16280.071*
C180.5266 (2)0.6652 (3)0.12437 (15)0.0702 (9)
H180.47210.70780.13280.084*
C190.5075 (2)0.5687 (3)0.09409 (16)0.0701 (9)
H190.44060.54650.08180.084*
C200.5886 (2)0.5059 (2)0.08241 (13)0.0545 (7)
H200.57560.44060.06250.065*
C210.77413 (18)0.46514 (18)0.08709 (10)0.0351 (5)
C221.03437 (19)0.4669 (2)0.10234 (11)0.0446 (6)
H221.04350.52920.12520.054*
C231.12506 (18)0.41165 (19)0.08684 (11)0.0414 (6)
C241.21444 (19)0.4029 (2)0.12690 (12)0.0469 (6)
C251.3026 (2)0.3577 (2)0.11159 (13)0.0537 (7)
H251.36160.35250.13850.064*
C261.3016 (2)0.3206 (2)0.05573 (14)0.0528 (7)
C271.2152 (2)0.3261 (2)0.01503 (13)0.0516 (7)
H271.21580.29980.02250.062*
C281.1275 (2)0.3719 (2)0.03130 (12)0.0468 (6)
H281.06870.37600.00420.056*
C290.7867 (2)0.3100 (2)0.06182 (12)0.0522 (7)
H290.73910.35050.04480.063*
C300.7740 (2)0.3005 (3)0.12136 (13)0.0640 (9)
H300.71860.33380.14370.077*
C310.8426 (3)0.2422 (3)0.14754 (13)0.0691 (9)
H310.83490.23440.18780.083*
C320.9237 (3)0.1952 (3)0.11271 (13)0.0749 (10)
H320.97280.15570.12910.090*
C330.9314 (2)0.2073 (2)0.05322 (12)0.0599 (8)
H330.98610.17440.03010.072*
C340.66922 (19)0.1427 (2)0.05502 (11)0.0478 (7)
H340.64260.21120.04460.057*
C350.6021 (2)0.0575 (2)0.05737 (13)0.0564 (7)
H350.53180.06860.04890.068*
C360.6398 (2)0.0433 (2)0.07224 (13)0.0604 (8)
H360.59580.10210.07380.072*
C370.7435 (2)0.0569 (2)0.08490 (13)0.0616 (8)
H370.77100.12490.09540.074*
C380.8065 (2)0.0320 (2)0.08182 (12)0.0516 (7)
H380.87690.02210.09050.062*
Cl10.89932 (6)0.51535 (7)0.27491 (4)0.0763 (3)
Cl20.49246 (6)0.46033 (9)0.24863 (4)0.0851 (3)
Cl31.21388 (6)0.44738 (7)0.19762 (3)0.0738 (2)
Cl41.41345 (6)0.26759 (7)0.03511 (5)0.0838 (3)
Co10.87434 (2)0.26990 (3)0.067207 (14)0.03589 (10)
H11.149 (2)0.196 (3)0.2236 (14)0.079 (12)*
H160.846 (3)0.634 (3)0.1355 (16)0.100 (14)*
N11.02840 (15)0.21304 (16)0.17093 (9)0.0406 (5)
N20.92933 (14)0.25629 (15)0.16358 (9)0.0374 (5)
N30.86780 (15)0.50435 (16)0.10100 (9)0.0396 (5)
N40.94306 (14)0.43349 (15)0.08595 (8)0.0370 (5)
N50.86424 (16)0.26376 (17)0.02715 (9)0.0439 (5)
N60.77133 (15)0.13159 (16)0.06701 (9)0.0408 (5)
O11.20508 (17)0.1707 (2)0.22773 (9)0.0692 (7)
O20.99765 (12)0.17201 (13)0.07302 (7)0.0397 (4)
O30.80262 (17)0.67721 (17)0.14589 (9)0.0606 (6)
O40.75276 (12)0.37119 (13)0.06474 (7)0.0419 (4)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.0347 (13)0.0391 (13)0.0397 (15)0.0035 (11)0.0050 (11)0.0079 (11)
C20.0418 (15)0.0583 (17)0.0398 (16)0.0097 (13)0.0021 (12)0.0072 (13)
C30.0376 (15)0.087 (2)0.0523 (19)0.0130 (15)0.0051 (13)0.0138 (16)
C40.0415 (16)0.093 (2)0.066 (2)0.0248 (16)0.0130 (15)0.0192 (18)
C50.0543 (18)0.086 (2)0.0520 (19)0.0229 (17)0.0140 (14)0.0014 (16)
C60.0465 (16)0.0593 (17)0.0430 (16)0.0125 (14)0.0028 (12)0.0008 (13)
C70.0348 (13)0.0315 (12)0.0389 (15)0.0007 (10)0.0011 (11)0.0053 (10)
C80.0460 (15)0.0539 (16)0.0350 (15)0.0073 (13)0.0039 (12)0.0026 (12)
C90.0464 (15)0.0499 (15)0.0310 (14)0.0077 (12)0.0069 (11)0.0035 (11)
C100.0470 (15)0.0560 (17)0.0360 (15)0.0020 (13)0.0017 (11)0.0024 (12)
C110.0589 (18)0.0598 (18)0.0440 (17)0.0124 (15)0.0085 (13)0.0091 (13)
C120.0488 (17)0.069 (2)0.0481 (18)0.0133 (15)0.0147 (13)0.0027 (15)
C130.0462 (16)0.0639 (19)0.060 (2)0.0035 (14)0.0093 (14)0.0003 (15)
C140.0531 (17)0.0478 (16)0.0469 (17)0.0038 (13)0.0101 (13)0.0051 (12)
C150.0404 (14)0.0334 (13)0.0442 (15)0.0017 (11)0.0096 (11)0.0044 (11)
C160.0493 (16)0.0386 (14)0.0454 (16)0.0037 (12)0.0107 (12)0.0028 (12)
C170.071 (2)0.0452 (16)0.066 (2)0.0084 (15)0.0253 (16)0.0031 (14)
C180.058 (2)0.056 (2)0.104 (3)0.0163 (16)0.0368 (18)0.0052 (18)
C190.0408 (16)0.057 (2)0.116 (3)0.0041 (15)0.0217 (17)0.0066 (19)
C200.0427 (15)0.0419 (15)0.080 (2)0.0006 (13)0.0122 (14)0.0005 (14)
C210.0375 (13)0.0322 (13)0.0354 (14)0.0029 (11)0.0039 (10)0.0028 (10)
C220.0401 (14)0.0399 (14)0.0534 (17)0.0035 (12)0.0051 (12)0.0027 (12)
C230.0340 (13)0.0370 (14)0.0531 (17)0.0039 (11)0.0055 (11)0.0034 (12)
C240.0388 (14)0.0467 (15)0.0542 (17)0.0033 (12)0.0026 (12)0.0035 (13)
C250.0360 (14)0.0523 (17)0.070 (2)0.0006 (13)0.0018 (13)0.0011 (15)
C260.0390 (15)0.0434 (15)0.079 (2)0.0000 (12)0.0196 (14)0.0012 (15)
C270.0527 (17)0.0523 (17)0.0527 (18)0.0029 (14)0.0176 (14)0.0039 (13)
C280.0418 (15)0.0506 (16)0.0477 (17)0.0024 (12)0.0049 (12)0.0060 (13)
C290.0456 (16)0.0614 (18)0.0474 (18)0.0039 (13)0.0011 (13)0.0063 (13)
C300.0603 (19)0.078 (2)0.048 (2)0.0065 (17)0.0109 (15)0.0132 (16)
C310.083 (2)0.086 (2)0.0353 (17)0.009 (2)0.0024 (16)0.0006 (16)
C320.094 (3)0.087 (2)0.0434 (19)0.019 (2)0.0076 (17)0.0079 (16)
C330.0655 (19)0.067 (2)0.0441 (18)0.0195 (16)0.0020 (14)0.0029 (14)
C340.0437 (15)0.0396 (15)0.0585 (18)0.0008 (12)0.0016 (12)0.0046 (12)
C350.0484 (16)0.0516 (17)0.069 (2)0.0060 (14)0.0081 (14)0.0086 (14)
C360.067 (2)0.0477 (17)0.067 (2)0.0162 (15)0.0113 (16)0.0042 (14)
C370.075 (2)0.0356 (15)0.074 (2)0.0010 (15)0.0081 (16)0.0064 (14)
C380.0497 (16)0.0417 (15)0.0614 (19)0.0032 (13)0.0010 (13)0.0003 (13)
Cl10.0597 (5)0.0816 (6)0.0836 (6)0.0050 (4)0.0037 (4)0.0258 (5)
Cl20.0551 (5)0.1155 (8)0.0891 (7)0.0219 (5)0.0260 (4)0.0083 (5)
Cl30.0667 (5)0.0908 (6)0.0597 (5)0.0029 (4)0.0064 (4)0.0201 (4)
Cl40.0486 (4)0.0769 (6)0.1316 (8)0.0043 (4)0.0327 (5)0.0163 (5)
Co10.03361 (18)0.03478 (17)0.0377 (2)0.00443 (14)0.00086 (13)0.00057 (14)
N10.0366 (11)0.0490 (12)0.0357 (12)0.0095 (10)0.0031 (9)0.0034 (10)
N20.0348 (11)0.0379 (11)0.0398 (12)0.0047 (9)0.0065 (9)0.0036 (9)
N30.0358 (11)0.0360 (11)0.0470 (13)0.0036 (9)0.0059 (9)0.0022 (9)
N40.0356 (11)0.0356 (11)0.0396 (12)0.0022 (9)0.0044 (9)0.0048 (9)
N50.0451 (12)0.0442 (12)0.0402 (12)0.0020 (10)0.0024 (10)0.0011 (10)
N60.0422 (12)0.0366 (11)0.0426 (13)0.0010 (9)0.0023 (9)0.0036 (9)
O10.0576 (14)0.1012 (18)0.0439 (13)0.0299 (13)0.0107 (10)0.0091 (11)
O20.0374 (9)0.0447 (10)0.0352 (10)0.0081 (8)0.0016 (7)0.0016 (7)
O30.0556 (13)0.0482 (12)0.0759 (15)0.0019 (11)0.0018 (11)0.0170 (10)
O40.0350 (9)0.0357 (9)0.0534 (11)0.0024 (7)0.0005 (8)0.0052 (8)
Geometric parameters (Å, º) top
C1—C61.388 (3)C22—H220.9300
C1—C21.407 (3)C23—C281.383 (3)
C1—C71.481 (3)C23—C241.401 (3)
C2—O11.350 (3)C24—C251.378 (4)
C2—C31.388 (4)C24—Cl31.731 (3)
C3—C41.368 (4)C25—C261.373 (4)
C3—H3A0.9300C25—H250.9300
C4—C51.379 (4)C26—C271.377 (4)
C4—H40.9300C26—Cl41.738 (3)
C5—C61.373 (4)C27—C281.384 (4)
C5—H50.9300C27—H270.9300
C6—H60.9300C28—H280.9300
C7—O21.286 (3)C29—N51.337 (3)
C7—N11.319 (3)C29—C301.374 (4)
C8—N21.281 (3)C29—H290.9300
C8—C91.460 (3)C30—C311.361 (4)
C8—H80.9300C30—H300.9300
C9—C101.391 (4)C31—C321.375 (4)
C9—C141.391 (3)C31—H310.9300
C10—C111.381 (4)C32—C331.379 (4)
C10—Cl11.738 (3)C32—H320.9300
C11—C121.370 (4)C33—N51.334 (3)
C11—H110.9300C33—H330.9300
C12—C131.374 (4)C34—N61.343 (3)
C12—Cl21.740 (3)C34—C351.377 (4)
C13—C141.386 (4)C34—H340.9300
C13—H130.9300C35—C361.360 (4)
C14—H140.9300C35—H350.9300
C15—C201.393 (3)C36—C371.368 (4)
C15—C161.409 (3)C36—H360.9300
C15—C211.481 (3)C37—C381.379 (4)
C16—O31.351 (3)C37—H370.9300
C16—C171.392 (4)C38—N61.336 (3)
C17—C181.368 (4)C38—H380.9300
C17—H170.9300Co1—O22.0112 (15)
C18—C191.384 (4)Co1—O42.0234 (16)
C18—H180.9300Co1—N62.174 (2)
C19—C201.376 (4)Co1—N52.177 (2)
C19—H190.9300Co1—N42.2219 (19)
C20—H200.9300Co1—N22.260 (2)
C21—O41.280 (3)N1—N21.398 (3)
C21—N31.323 (3)N3—N41.400 (3)
C22—N41.279 (3)O1—H10.80 (3)
C22—C231.462 (3)O3—H160.84 (4)
C6—C1—C2118.0 (2)C24—C25—H25120.7
C6—C1—C7119.8 (2)C25—C26—C27122.1 (3)
C2—C1—C7122.2 (2)C25—C26—Cl4119.1 (2)
O1—C2—C3118.1 (2)C27—C26—Cl4118.8 (2)
O1—C2—C1122.6 (2)C26—C27—C28118.4 (3)
C3—C2—C1119.3 (3)C26—C27—H27120.8
C4—C3—C2121.0 (3)C28—C27—H27120.8
C4—C3—H3A119.5C23—C28—C27121.7 (2)
C2—C3—H3A119.5C23—C28—H28119.2
C3—C4—C5120.3 (3)C27—C28—H28119.2
C3—C4—H4119.9N5—C29—C30123.1 (3)
C5—C4—H4119.9N5—C29—H29118.4
C6—C5—C4119.2 (3)C30—C29—H29118.4
C6—C5—H5120.4C31—C30—C29119.8 (3)
C4—C5—H5120.4C31—C30—H30120.1
C5—C6—C1122.1 (2)C29—C30—H30120.1
C5—C6—H6119.0C30—C31—C32118.0 (3)
C1—C6—H6119.0C30—C31—H31121.0
O2—C7—N1124.8 (2)C32—C31—H31121.0
O2—C7—C1118.6 (2)C31—C32—C33119.1 (3)
N1—C7—C1116.6 (2)C31—C32—H32120.4
N2—C8—C9124.1 (2)C33—C32—H32120.4
N2—C8—H8118.0N5—C33—C32123.3 (3)
C9—C8—H8118.0N5—C33—H33118.3
C10—C9—C14116.8 (2)C32—C33—H33118.3
C10—C9—C8121.7 (2)N6—C34—C35123.1 (2)
C14—C9—C8121.3 (2)N6—C34—H34118.5
C11—C10—C9122.5 (2)C35—C34—H34118.5
C11—C10—Cl1118.4 (2)C36—C35—C34119.1 (3)
C9—C10—Cl1119.2 (2)C36—C35—H35120.4
C12—C11—C10118.5 (3)C34—C35—H35120.4
C12—C11—H11120.7C35—C36—C37119.0 (3)
C10—C11—H11120.7C35—C36—H36120.5
C11—C12—C13121.5 (3)C37—C36—H36120.5
C11—C12—Cl2118.9 (2)C36—C37—C38118.9 (3)
C13—C12—Cl2119.6 (2)C36—C37—H37120.5
C12—C13—C14118.9 (3)C38—C37—H37120.5
C12—C13—H13120.5N6—C38—C37123.2 (3)
C14—C13—H13120.5N6—C38—H38118.4
C13—C14—C9121.7 (3)C37—C38—H38118.4
C13—C14—H14119.1O2—Co1—O4177.51 (6)
C9—C14—H14119.1O2—Co1—N691.84 (7)
C20—C15—C16118.0 (2)O4—Co1—N689.31 (7)
C20—C15—C21119.6 (2)O2—Co1—N589.05 (7)
C16—C15—C21122.4 (2)O4—Co1—N593.13 (7)
O3—C16—C17117.6 (2)N6—Co1—N591.11 (8)
O3—C16—C15122.9 (2)O2—Co1—N4102.90 (7)
C17—C16—C15119.5 (3)O4—Co1—N475.51 (7)
C18—C17—C16120.9 (3)N6—Co1—N4160.80 (8)
C18—C17—H17119.5N5—Co1—N4101.24 (7)
C16—C17—H17119.5O2—Co1—N275.15 (7)
C17—C18—C19120.4 (3)O4—Co1—N2102.59 (7)
C17—C18—H18119.8N6—Co1—N293.40 (7)
C19—C18—H18119.8N5—Co1—N2163.68 (7)
C20—C19—C18119.3 (3)N4—Co1—N278.85 (7)
C20—C19—H19120.4C7—N1—N2113.07 (18)
C18—C19—H19120.4C8—N2—N1113.06 (19)
C19—C20—C15121.9 (3)C8—N2—Co1134.96 (16)
C19—C20—H20119.1N1—N2—Co1108.38 (14)
C15—C20—H20119.1C21—N3—N4112.49 (19)
O4—C21—N3124.9 (2)C22—N4—N3113.4 (2)
O4—C21—C15119.3 (2)C22—N4—Co1133.59 (17)
N3—C21—C15115.8 (2)N3—N4—Co1109.09 (13)
N4—C22—C23123.1 (2)C33—N5—C29116.6 (2)
N4—C22—H22118.4C33—N5—Co1121.49 (17)
C23—C22—H22118.4C29—N5—Co1121.76 (19)
C28—C23—C24117.8 (2)C38—N6—C34116.7 (2)
C28—C23—C22121.2 (2)C38—N6—Co1121.33 (17)
C24—C23—C22120.9 (2)C34—N6—Co1121.91 (17)
C25—C24—C23121.5 (3)C2—O1—H1112 (2)
C25—C24—Cl3119.1 (2)C7—O2—Co1115.55 (15)
C23—C24—Cl3119.5 (2)C16—O3—H16109 (3)
C26—C25—C24118.6 (2)C21—O4—Co1114.42 (14)
C26—C25—H25120.7
C6—C1—C2—O1179.3 (3)C9—C8—N2—Co131.0 (4)
C7—C1—C2—O11.2 (4)C7—N1—N2—C8175.9 (2)
C6—C1—C2—C31.9 (4)C7—N1—N2—Co114.0 (2)
C7—C1—C2—C3177.6 (2)O2—Co1—N2—C8171.0 (2)
O1—C2—C3—C4178.6 (3)O4—Co1—N2—C88.0 (2)
C1—C2—C3—C42.6 (4)N6—Co1—N2—C898.0 (2)
C2—C3—C4—C51.4 (5)N5—Co1—N2—C8156.2 (3)
C3—C4—C5—C60.4 (5)N4—Co1—N2—C864.3 (2)
C4—C5—C6—C11.0 (5)O2—Co1—N2—N114.76 (13)
C2—C1—C6—C50.2 (4)O4—Co1—N2—N1164.18 (13)
C7—C1—C6—C5179.3 (3)N6—Co1—N2—N1105.77 (14)
C6—C1—C7—O25.6 (3)N5—Co1—N2—N10.0 (3)
C2—C1—C7—O2174.0 (2)N4—Co1—N2—N191.96 (14)
C6—C1—C7—N1174.6 (2)O4—C21—N3—N43.0 (3)
C2—C1—C7—N15.9 (3)C15—C21—N3—N4177.76 (19)
N2—C8—C9—C10145.2 (3)C23—C22—N4—N3174.2 (2)
N2—C8—C9—C1439.7 (4)C23—C22—N4—Co131.2 (4)
C14—C9—C10—C110.4 (4)C21—N3—N4—C22175.8 (2)
C8—C9—C10—C11174.9 (2)C21—N3—N4—Co115.0 (2)
C14—C9—C10—Cl1179.36 (19)O2—Co1—N4—C226.5 (2)
C8—C9—C10—Cl15.3 (3)O4—Co1—N4—C22171.5 (2)
C9—C10—C11—C120.6 (4)N6—Co1—N4—C22132.8 (3)
Cl1—C10—C11—C12179.7 (2)N5—Co1—N4—C2298.1 (2)
C10—C11—C12—C130.8 (4)N2—Co1—N4—C2265.2 (2)
C10—C11—C12—Cl2178.0 (2)O2—Co1—N4—N3161.98 (13)
C11—C12—C13—C140.2 (4)O4—Co1—N4—N316.06 (13)
Cl2—C12—C13—C14178.7 (2)N6—Co1—N4—N322.7 (3)
C12—C13—C14—C90.8 (4)N5—Co1—N4—N3106.41 (14)
C10—C9—C14—C131.1 (4)N2—Co1—N4—N390.23 (14)
C8—C9—C14—C13174.3 (2)C32—C33—N5—C290.1 (4)
C20—C15—C16—O3177.4 (2)C32—C33—N5—Co1175.4 (2)
C21—C15—C16—O33.4 (4)C30—C29—N5—C330.7 (4)
C20—C15—C16—C172.2 (4)C30—C29—N5—Co1174.9 (2)
C21—C15—C16—C17177.0 (2)O2—Co1—N5—C330.6 (2)
O3—C16—C17—C18177.3 (3)O4—Co1—N5—C33178.2 (2)
C15—C16—C17—C182.4 (4)N6—Co1—N5—C3392.4 (2)
C16—C17—C18—C190.9 (5)N4—Co1—N5—C33102.4 (2)
C17—C18—C19—C200.7 (5)N2—Co1—N5—C3313.7 (4)
C18—C19—C20—C150.8 (5)O2—Co1—N5—C29174.7 (2)
C16—C15—C20—C190.7 (4)O4—Co1—N5—C296.5 (2)
C21—C15—C20—C19178.5 (3)N6—Co1—N5—C2982.9 (2)
C20—C15—C21—O45.4 (4)N4—Co1—N5—C2982.3 (2)
C16—C15—C21—O4173.7 (2)N2—Co1—N5—C29171.0 (2)
C20—C15—C21—N3175.3 (2)C37—C38—N6—C340.2 (4)
C16—C15—C21—N35.6 (3)C37—C38—N6—Co1176.9 (2)
N4—C22—C23—C2842.1 (4)C35—C34—N6—C380.1 (4)
N4—C22—C23—C24141.6 (3)C35—C34—N6—Co1176.7 (2)
C28—C23—C24—C250.9 (4)O2—Co1—N6—C3813.6 (2)
C22—C23—C24—C25175.5 (2)O4—Co1—N6—C38164.2 (2)
C28—C23—C24—Cl3177.86 (19)N5—Co1—N6—C38102.7 (2)
C22—C23—C24—Cl35.7 (3)N4—Co1—N6—C38126.9 (2)
C23—C24—C25—C260.2 (4)N2—Co1—N6—C3861.6 (2)
Cl3—C24—C25—C26178.6 (2)O2—Co1—N6—C34169.89 (19)
C24—C25—C26—C270.7 (4)O4—Co1—N6—C3412.31 (19)
C24—C25—C26—Cl4177.9 (2)N5—Co1—N6—C3480.8 (2)
C25—C26—C27—C280.8 (4)N4—Co1—N6—C3449.6 (3)
Cl4—C26—C27—C28177.8 (2)N2—Co1—N6—C34114.89 (19)
C24—C23—C28—C270.9 (4)N1—C7—O2—Co111.2 (3)
C22—C23—C28—C27175.5 (2)C1—C7—O2—Co1168.56 (16)
C26—C27—C28—C230.1 (4)O4—Co1—O2—C710.9 (17)
N5—C29—C30—C310.4 (5)N6—Co1—O2—C7106.70 (17)
C29—C30—C31—C320.5 (5)N5—Co1—O2—C7162.22 (17)
C30—C31—C32—C331.0 (5)N4—Co1—O2—C760.90 (17)
C31—C32—C33—N50.7 (5)N2—Co1—O2—C713.68 (16)
N6—C34—C35—C360.3 (4)N3—C21—O4—Co112.5 (3)
C34—C35—C36—C370.5 (4)C15—C21—O4—Co1166.72 (16)
C35—C36—C37—C380.4 (5)O2—Co1—O4—C2135.5 (17)
C36—C37—C38—N60.1 (5)N6—Co1—O4—C21153.12 (17)
O2—C7—N1—N23.4 (3)N5—Co1—O4—C21115.80 (17)
C1—C7—N1—N2176.80 (19)N4—Co1—O4—C2114.99 (16)
C9—C8—N2—N1173.6 (2)N2—Co1—O4—C2159.80 (17)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1—H1···N10.80 (3)1.87 (3)2.566 (3)144 (3)
O3—H16···N30.84 (4)1.83 (4)2.564 (3)146 (3)
 

Footnotes

1.

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