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Acta Cryst. (2007). E63, m1004-m1005  [ doi:10.1107/S1600536807009919 ]

Bis(tetrabutylammonium) di-[mu]-bromido-bis[dibromidopalladate(II)]

Y.-L. Zhu, L.-S. Wang, Q. Li and Y.-G. Wei

Abstract: The title compound, (C16H36N)2[Pd2Br6], was prepared from palladium(II) bromide and tetrabutylammonium bromide. In the anion, the terminal and bridging Pd-Br bond lengths lie in the ranges 2.3982 (9)-2.4185 (8) and 2.4389 (7)-2.4513 (7) Å, respectively. The anion can be viewed as a dimeric cluster consiting of two edge-sharing PdBr4 square units, which make a dihedral angle of 7.84 (4)°.

Online 14 March 2007


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