Acta Cryst. (2007). E63, m1073-m1075  [ doi:10.1107/S1600536807011865 ]

catena-Poly[[[diaqua(isophthalato)]cobalt(II)]--1,4-diazabicyclo[2.2.2]octane] N,N-dimethylformamide solvate]: a chiral one-dimensional coordination polymer

A.-Q. Ma

Abstract: In the title compound, {[Co(C₈H₄O₄)(C₆H₁₂N₂)(H₂O)₂]·C₃H₇NO}_n, the Co atom is coordinated by the two N atoms from two 1,4-diazabicyclo[2.2.2]octane (dabco) ligands, two O atoms from two isophthalate dianions and two water molecules in a distorted octahedral geometry. The dabco molecules function as ₂-bridging ligands, forming polymeric linear chains running along the c axis. The crystal structure is stabilized by intermolecular O-HO hydrogen bonds.

Online 21 March 2007

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