A linear coordination geometry defined by S and P atoms is found for Au in both components of the title 1:1 cocrystal, [Au(C
6H
15P)(C
11H
12NO
3S)]·[Au(C
6H
15P)(C
12H
14NO
3S)]. Pairs of molecules disordered over an inversion centre associate
via Au
·S interactions and these dimeric units are connected into chains
via C—H
O interactions.
Supporting information
CCDC reference: 643001
Key indicators
- Single-crystal X-ray study
- T = 223 K
- Mean (C-C) = 0.008 Å
- Disorder in main residue
- R factor = 0.031
- wR factor = 0.078
- Data-to-parameter ratio = 18.6
checkCIF/PLATON results
No syntax errors found
Alert level B
PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.57 Ratio
PLAT241_ALERT_2_B Check High Ueq as Compared to Neighbors for C9
Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.81
PLAT301_ALERT_3_C Main Residue Disorder ......................... 12.00 Perc.
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 3
Alert level G
ABSTM02_ALERT_3_G When printed, the submitted absorption T values will be
replaced by the scaled T values. Since the ratio of scaled T's
is identical to the ratio of reported T values, the scaling
does not imply a change to the absorption corrections used in
the study.
Ratio of Tmax expected/reported 0.806
Tmax scaled 0.806 Tmin scaled 0.256
0 ALERT level A = In general: serious problem
2 ALERT level B = Potentially serious problem
4 ALERT level C = Check and explain
1 ALERT level G = General alerts; check
1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
2 ALERT type 2 Indicator that the structure model may be wrong or deficient
2 ALERT type 3 Indicator that the structure quality may be low
2 ALERT type 4 Improvement, methodology, query or suggestion
0 ALERT type 5 Informative message, check
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: PATTY in DIRDIF92 (Beurskens et al., 1992); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976) and DIAMOND (Brandenburg, 2006); software used to prepare material for publication: SHELXL97.
{
O-Ethyl (
Z)-[4-(methoxycarbonyl)phenyl]thiocarbamato-
κS}(triethylphosphine-
κP)gold(I)– {
O-ethyl
(
Z)-[4-(ethoxycarbonyl)phenyl]thiocarbamato-
κS}(triethylphosphine-
κP)gold(I) (1/1)
top
Crystal data top
[Au(C6H15P)(C11H12NO3S)]·[Au(C6H15P)(C12H14NO3S)] | Z = 1 |
Mr = 1120.81 | F(000) = 548 |
Triclinic, P1 | Dx = 1.772 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71069 Å |
a = 7.6246 (3) Å | Cell parameters from 3917 reflections |
b = 10.3422 (4) Å | θ = 2.7–29.9° |
c = 14.5155 (5) Å | µ = 7.20 mm−1 |
α = 79.678 (2)° | T = 223 K |
β = 79.451 (1)° | Plate, colourless |
γ = 70.188 (2)° | 0.34 × 0.10 × 0.03 mm |
V = 1050.15 (7) Å3 | |
Data collection top
Bruker SMART CCD diffractometer | 4806 independent reflections |
Radiation source: fine-focus sealed tube | 4294 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.028 |
ω scans | θmax = 27.5°, θmin = 2.1° |
Absorption correction: multi-scan (SADABS; Bruker, 2000) | h = −9→9 |
Tmin = 0.318, Tmax = 1 | k = −10→13 |
7470 measured reflections | l = −18→18 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.031 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.078 | H-atom parameters constrained |
S = 1.00 | w = 1/[σ2(Fo2) + (0.0402P)2] where P = (Fo2 + 2Fc2)/3 |
4806 reflections | (Δ/σ)max < 0.001 |
259 parameters | Δρmax = 1.48 e Å−3 |
53 restraints | Δρmin = −1.52 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Au | 0.72752 (2) | 0.371568 (16) | 0.534748 (12) | 0.02664 (7) | |
S1 | 0.65345 (16) | 0.33583 (12) | 0.39585 (9) | 0.0313 (3) | |
P1 | 0.81159 (17) | 0.39341 (12) | 0.67109 (9) | 0.0257 (2) | |
O1 | 0.2822 (17) | 0.1792 (12) | 0.0204 (11) | 0.058 (4) | 0.50 |
O2 | 0.290 (3) | 0.3987 (13) | −0.0165 (11) | 0.057 (4) | 0.50 |
O1' | 0.2306 (15) | 0.2067 (12) | 0.0358 (10) | 0.051 (3) | 0.50 |
O2' | 0.328 (3) | 0.3813 (12) | −0.0329 (10) | 0.051 (4) | 0.50 |
O3 | 0.9864 (4) | 0.1589 (3) | 0.4144 (2) | 0.0296 (7) | |
N1 | 0.8617 (6) | 0.1273 (4) | 0.2930 (3) | 0.0312 (9) | |
C1 | 0.8473 (6) | 0.1947 (4) | 0.3597 (3) | 0.0250 (9) | |
C2 | 0.7267 (7) | 0.1692 (5) | 0.2307 (3) | 0.0296 (10) | |
C3 | 0.7032 (8) | 0.2894 (5) | 0.1677 (4) | 0.0380 (12) | |
H3 | 0.7727 | 0.3482 | 0.1700 | 0.046* | |
C4 | 0.5809 (8) | 0.3251 (6) | 0.1018 (4) | 0.0399 (12) | |
H4 | 0.5668 | 0.4075 | 0.0600 | 0.048* | |
C5 | 0.4769 (7) | 0.2379 (5) | 0.0972 (3) | 0.0348 (11) | |
C6 | 0.4990 (7) | 0.1185 (5) | 0.1604 (4) | 0.0383 (12) | |
H6 | 0.4289 | 0.0600 | 0.1586 | 0.046* | |
C7 | 0.6225 (7) | 0.0839 (5) | 0.2261 (4) | 0.0369 (11) | |
H7 | 0.6363 | 0.0018 | 0.2682 | 0.044* | |
C8 | 0.3389 (6) | 0.2830 (5) | 0.0268 (3) | 0.0465 (14) | |
C9 | 0.146 (2) | 0.2083 (19) | −0.0458 (12) | 0.090 (7) | 0.50 |
H9A | 0.2131 | 0.2029 | −0.1102 | 0.108* | 0.50 |
H9B | 0.0593 | 0.3026 | −0.0429 | 0.108* | 0.50 |
C10 | 0.038 (2) | 0.1079 (16) | −0.0236 (11) | 0.068 (4) | 0.50 |
H10A | −0.0680 | 0.1408 | −0.0593 | 0.102* | 0.50 |
H10B | −0.0077 | 0.0996 | 0.0434 | 0.102* | 0.50 |
H10C | 0.1188 | 0.0181 | −0.0404 | 0.102* | 0.50 |
C9' | 0.0904 (19) | 0.2423 (17) | −0.0291 (10) | 0.060 (4) | 0.50 |
H9'A | 0.0419 | 0.1657 | −0.0247 | 0.090* | 0.50 |
H9'B | 0.1484 | 0.2606 | −0.0932 | 0.090* | 0.50 |
H9'C | −0.0119 | 0.3242 | −0.0124 | 0.090* | 0.50 |
C11 | 1.1513 (6) | 0.0435 (5) | 0.3880 (4) | 0.0318 (10) | |
H11A | 1.1989 | 0.0599 | 0.3210 | 0.038* | |
H11B | 1.1198 | −0.0429 | 0.3992 | 0.038* | |
C12 | 1.2959 (7) | 0.0345 (6) | 0.4488 (4) | 0.0405 (12) | |
H12A | 1.4030 | −0.0479 | 0.4393 | 0.061* | |
H12B | 1.2413 | 0.0298 | 0.5146 | 0.061* | |
H12C | 1.3366 | 0.1159 | 0.4315 | 0.061* | |
C13 | 0.8288 (7) | 0.5616 (5) | 0.6800 (4) | 0.0310 (10) | |
H13A | 0.9014 | 0.5907 | 0.6219 | 0.037* | |
H13B | 0.7020 | 0.6289 | 0.6839 | 0.037* | |
C14 | 0.9197 (8) | 0.5667 (5) | 0.7640 (4) | 0.0403 (12) | |
H14A | 0.9081 | 0.6620 | 0.7679 | 0.060* | |
H14B | 1.0516 | 0.5121 | 0.7559 | 0.060* | |
H14C | 0.8570 | 0.5294 | 0.8217 | 0.060* | |
C15 | 1.0416 (7) | 0.2701 (5) | 0.6884 (4) | 0.0328 (11) | |
H15A | 1.0700 | 0.2736 | 0.7509 | 0.039* | |
H15B | 1.0395 | 0.1764 | 0.6866 | 0.039* | |
C16 | 1.1957 (7) | 0.3000 (6) | 0.6133 (5) | 0.0461 (14) | |
H16A | 1.3132 | 0.2258 | 0.6202 | 0.069* | |
H16B | 1.2104 | 0.3869 | 0.6207 | 0.069* | |
H16C | 1.1616 | 0.3061 | 0.5511 | 0.069* | |
C17 | 0.6556 (8) | 0.3566 (5) | 0.7750 (4) | 0.0374 (12) | |
H17A | 0.7035 | 0.3648 | 0.8312 | 0.045* | |
H17B | 0.5313 | 0.4264 | 0.7725 | 0.045* | |
C18 | 0.6345 (10) | 0.2131 (6) | 0.7851 (5) | 0.0572 (17) | |
H18A | 0.5465 | 0.2012 | 0.8408 | 0.086* | |
H18B | 0.7558 | 0.1430 | 0.7913 | 0.086* | |
H18C | 0.5877 | 0.2038 | 0.7296 | 0.086* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Au | 0.02665 (10) | 0.02687 (11) | 0.02695 (11) | −0.00364 (7) | −0.00873 (7) | −0.00907 (7) |
S1 | 0.0253 (6) | 0.0338 (6) | 0.0321 (7) | 0.0045 (5) | −0.0147 (5) | −0.0137 (5) |
P1 | 0.0287 (6) | 0.0254 (6) | 0.0245 (6) | −0.0063 (5) | −0.0084 (5) | −0.0066 (5) |
O1 | 0.065 (7) | 0.065 (6) | 0.056 (7) | −0.019 (5) | −0.035 (6) | −0.016 (5) |
O2 | 0.058 (8) | 0.070 (7) | 0.036 (6) | −0.012 (5) | −0.020 (5) | 0.013 (5) |
O1' | 0.036 (5) | 0.072 (7) | 0.046 (6) | −0.015 (5) | −0.016 (4) | −0.006 (5) |
O2' | 0.051 (7) | 0.066 (7) | 0.033 (6) | −0.015 (5) | −0.013 (5) | 0.003 (5) |
O3 | 0.0223 (15) | 0.0296 (16) | 0.0338 (19) | 0.0025 (13) | −0.0111 (13) | −0.0097 (14) |
N1 | 0.036 (2) | 0.027 (2) | 0.031 (2) | −0.0034 (16) | −0.0128 (18) | −0.0108 (17) |
C1 | 0.026 (2) | 0.023 (2) | 0.025 (2) | −0.0025 (17) | −0.0080 (18) | −0.0048 (17) |
C2 | 0.031 (2) | 0.029 (2) | 0.028 (3) | −0.0034 (19) | −0.0057 (19) | −0.0105 (19) |
C3 | 0.051 (3) | 0.032 (3) | 0.037 (3) | −0.016 (2) | −0.020 (2) | −0.002 (2) |
C4 | 0.056 (3) | 0.038 (3) | 0.030 (3) | −0.017 (2) | −0.019 (2) | 0.003 (2) |
C5 | 0.040 (3) | 0.041 (3) | 0.025 (3) | −0.010 (2) | −0.011 (2) | −0.007 (2) |
C6 | 0.041 (3) | 0.037 (3) | 0.041 (3) | −0.012 (2) | −0.014 (2) | −0.005 (2) |
C7 | 0.046 (3) | 0.029 (2) | 0.036 (3) | −0.010 (2) | −0.014 (2) | 0.001 (2) |
C8 | 0.049 (3) | 0.065 (4) | 0.027 (3) | −0.017 (3) | −0.009 (2) | −0.007 (3) |
C9 | 0.099 (11) | 0.101 (11) | 0.089 (11) | −0.035 (8) | −0.047 (8) | −0.016 (8) |
C10 | 0.053 (6) | 0.102 (8) | 0.064 (7) | −0.027 (6) | −0.020 (6) | −0.029 (6) |
C9' | 0.058 (7) | 0.084 (8) | 0.042 (7) | −0.019 (6) | −0.030 (6) | −0.002 (6) |
C11 | 0.028 (2) | 0.027 (2) | 0.035 (3) | 0.0025 (18) | −0.006 (2) | −0.010 (2) |
C12 | 0.029 (3) | 0.038 (3) | 0.051 (4) | −0.001 (2) | −0.013 (2) | −0.008 (2) |
C13 | 0.034 (2) | 0.028 (2) | 0.034 (3) | −0.0095 (19) | −0.009 (2) | −0.0069 (19) |
C14 | 0.043 (3) | 0.040 (3) | 0.046 (3) | −0.014 (2) | −0.010 (2) | −0.020 (2) |
C15 | 0.038 (3) | 0.027 (2) | 0.034 (3) | −0.0040 (19) | −0.015 (2) | −0.006 (2) |
C16 | 0.032 (3) | 0.043 (3) | 0.058 (4) | 0.000 (2) | −0.006 (3) | −0.015 (3) |
C17 | 0.047 (3) | 0.037 (3) | 0.031 (3) | −0.019 (2) | 0.004 (2) | −0.012 (2) |
C18 | 0.082 (5) | 0.054 (4) | 0.050 (4) | −0.044 (3) | 0.011 (3) | −0.017 (3) |
Geometric parameters (Å, º) top
Au—S1 | 2.3122 (12) | C10—H10A | 0.9700 |
Au—P1 | 2.2587 (12) | C10—H10B | 0.9700 |
S1—C1 | 1.766 (4) | C10—H10C | 0.9700 |
P1—C17 | 1.811 (5) | C9'—H9'A | 0.9700 |
P1—C15 | 1.815 (5) | C9'—H9'B | 0.9700 |
P1—C13 | 1.817 (5) | C9'—H9'C | 0.9700 |
O1—C8 | 1.308 (9) | C11—C12 | 1.503 (7) |
O1—C9 | 1.461 (9) | C11—H11A | 0.9800 |
O2—C8 | 1.216 (9) | C11—H11B | 0.9800 |
O1'—C8 | 1.299 (8) | C12—H12A | 0.9700 |
O1'—C9' | 1.463 (9) | C12—H12B | 0.9700 |
O2'—C8 | 1.201 (9) | C12—H12C | 0.9700 |
O3—C1 | 1.352 (5) | C13—C14 | 1.526 (7) |
O3—C11 | 1.457 (5) | C13—H13A | 0.9800 |
N1—C1 | 1.261 (6) | C13—H13B | 0.9800 |
N1—C2 | 1.401 (6) | C14—H14A | 0.9700 |
C2—C3 | 1.384 (7) | C14—H14B | 0.9700 |
C2—C7 | 1.389 (7) | C14—H14C | 0.9700 |
C3—C4 | 1.373 (7) | C15—C16 | 1.524 (8) |
C3—H3 | 0.9400 | C15—H15A | 0.9800 |
C4—C5 | 1.404 (7) | C15—H15B | 0.9800 |
C4—H4 | 0.9400 | C16—H16A | 0.9700 |
C5—C6 | 1.379 (7) | C16—H16B | 0.9700 |
C5—C8 | 1.503 (7) | C16—H16C | 0.9700 |
C6—C7 | 1.380 (7) | C17—C18 | 1.525 (7) |
C6—H6 | 0.9400 | C17—H17A | 0.9800 |
C7—H7 | 0.9400 | C17—H17B | 0.9800 |
C9—C10 | 1.494 (10) | C18—H18A | 0.9700 |
C9—H9A | 0.9800 | C18—H18B | 0.9700 |
C9—H9B | 0.9800 | C18—H18C | 0.9700 |
| | | |
S1—Au—P1 | 176.60 (4) | H9'A—C9'—H9'C | 109.5 |
Au—S1—C1 | 103.11 (16) | H9'B—C9'—H9'C | 109.5 |
C17—P1—C15 | 105.3 (2) | O3—C11—C12 | 106.3 (4) |
C17—P1—C13 | 105.4 (2) | O3—C11—H11A | 110.5 |
C15—P1—C13 | 105.5 (2) | C12—C11—H11A | 110.5 |
C17—P1—Au | 113.57 (18) | O3—C11—H11B | 110.5 |
C15—P1—Au | 110.17 (17) | C12—C11—H11B | 110.5 |
C13—P1—Au | 116.10 (17) | H11A—C11—H11B | 108.7 |
C8—O1—C9 | 115.4 (12) | C11—C12—H12A | 109.5 |
C8—O1'—C9' | 118.6 (13) | C11—C12—H12B | 109.5 |
C1—O3—C11 | 115.5 (4) | H12A—C12—H12B | 109.5 |
C1—N1—C2 | 121.5 (4) | C11—C12—H12C | 109.5 |
N1—C1—O3 | 120.5 (4) | H12A—C12—H12C | 109.5 |
N1—C1—S1 | 126.7 (4) | H12B—C12—H12C | 109.5 |
O3—C1—S1 | 112.7 (3) | C14—C13—P1 | 115.2 (3) |
C3—C2—C7 | 118.2 (5) | C14—C13—H13A | 108.5 |
C3—C2—N1 | 121.8 (4) | P1—C13—H13A | 108.5 |
C7—C2—N1 | 119.8 (4) | C14—C13—H13B | 108.5 |
C4—C3—C2 | 121.7 (5) | P1—C13—H13B | 108.5 |
C4—C3—H3 | 119.1 | H13A—C13—H13B | 107.5 |
C2—C3—H3 | 119.1 | C13—C14—H14A | 109.5 |
C3—C4—C5 | 119.8 (5) | C13—C14—H14B | 109.5 |
C3—C4—H4 | 120.1 | H14A—C14—H14B | 109.5 |
C5—C4—H4 | 120.1 | C13—C14—H14C | 109.5 |
C6—C5—C4 | 118.7 (5) | H14A—C14—H14C | 109.5 |
C6—C5—C8 | 123.0 (4) | H14B—C14—H14C | 109.5 |
C4—C5—C8 | 118.3 (4) | C16—C15—P1 | 112.0 (4) |
C5—C6—C7 | 120.9 (5) | C16—C15—H15A | 109.2 |
C5—C6—H6 | 119.5 | P1—C15—H15A | 109.2 |
C7—C6—H6 | 119.5 | C16—C15—H15B | 109.2 |
C6—C7—C2 | 120.7 (5) | P1—C15—H15B | 109.2 |
C6—C7—H7 | 119.6 | H15A—C15—H15B | 107.9 |
C2—C7—H7 | 119.6 | C15—C16—H16A | 109.5 |
O2'—C8—O1' | 122.5 (16) | C15—C16—H16B | 109.5 |
O2—C8—O1' | 118.3 (15) | H16A—C16—H16B | 109.5 |
O2'—C8—O1 | 123.9 (15) | C15—C16—H16C | 109.5 |
O2—C8—O1 | 126.5 (16) | H16A—C16—H16C | 109.5 |
O2'—C8—C5 | 123.3 (14) | H16B—C16—H16C | 109.5 |
O2—C8—C5 | 124.2 (15) | C18—C17—P1 | 113.7 (4) |
O1'—C8—C5 | 114.3 (8) | C18—C17—H17A | 108.8 |
O1—C8—C5 | 109.3 (8) | P1—C17—H17A | 108.8 |
O1—C9—C10 | 111.4 (11) | C18—C17—H17B | 108.8 |
O1—C9—H9A | 109.4 | P1—C17—H17B | 108.8 |
C10—C9—H9A | 109.4 | H17A—C17—H17B | 107.7 |
O1—C9—H9B | 109.4 | C17—C18—H18A | 109.5 |
C10—C9—H9B | 109.4 | C17—C18—H18B | 109.5 |
H9A—C9—H9B | 108.0 | H18A—C18—H18B | 109.5 |
O1'—C9'—H9'A | 109.5 | C17—C18—H18C | 109.5 |
O1'—C9'—H9'B | 109.5 | H18A—C18—H18C | 109.5 |
H9'A—C9'—H9'B | 109.5 | H18B—C18—H18C | 109.5 |
O1'—C9'—H9'C | 109.5 | | |
| | | |
C2—N1—C1—O3 | −174.7 (4) | C9—O1—C8—O2 | 0.1 (4) |
C2—N1—C1—S1 | 7.5 (7) | C9—O1—C8—O1' | 72 (4) |
C11—O3—C1—N1 | 2.3 (6) | C9—O1—C8—C5 | 179.9 (2) |
C11—O3—C1—S1 | −179.6 (3) | C6—C5—C8—O2' | −174.4 (8) |
Au—S1—C1—N1 | 171.4 (4) | C4—C5—C8—O2' | 8.9 (7) |
Au—S1—C1—O3 | −6.5 (3) | C6—C5—C8—O2 | 164.9 (8) |
C1—N1—C2—C3 | 67.7 (7) | C4—C5—C8—O2 | −11.7 (8) |
C1—N1—C2—C7 | −117.3 (5) | C6—C5—C8—O1' | 5.7 (8) |
C7—C2—C3—C4 | −0.1 (8) | C4—C5—C8—O1' | −171.0 (7) |
N1—C2—C3—C4 | 175.0 (5) | C6—C5—C8—O1 | −14.9 (7) |
C2—C3—C4—C5 | −0.3 (9) | C4—C5—C8—O1 | 168.4 (7) |
C3—C4—C5—C6 | 0.8 (8) | C8—O1—C9—C10 | −158.9 (15) |
C3—C4—C5—C8 | 177.6 (5) | C1—O3—C11—C12 | 172.5 (4) |
C4—C5—C6—C7 | −0.9 (8) | C17—P1—C13—C14 | 64.1 (4) |
C8—C5—C6—C7 | −177.6 (5) | C15—P1—C13—C14 | −47.0 (4) |
C5—C6—C7—C2 | 0.5 (9) | Au—P1—C13—C14 | −169.3 (3) |
C3—C2—C7—C6 | 0.0 (8) | C17—P1—C15—C16 | −172.0 (4) |
N1—C2—C7—C6 | −175.2 (5) | C13—P1—C15—C16 | −60.9 (4) |
C9'—O1'—C8—O2' | −0.2 (4) | Au—P1—C15—C16 | 65.1 (4) |
C9'—O1'—C8—O2 | 19.1 (12) | C15—P1—C17—C18 | −64.1 (5) |
C9'—O1'—C8—O1 | −101 (4) | C13—P1—C17—C18 | −175.4 (5) |
C9'—O1'—C8—C5 | 179.7 (3) | Au—P1—C17—C18 | 56.4 (5) |
C9—O1—C8—O2' | −20.7 (12) | | |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
C4—H4···O2i | 0.94 | 2.53 | 3.295 (18) | 139 |
C4—H4···O2′i | 0.94 | 2.52 | 3.285 (17) | 139 |
Symmetry code: (i) −x+1, −y+1, −z. |