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The centrosymmetric mol­ecules of the title compound, [Na4(P14)(C4H10O2)8], contain two P7 clusters connected by a P—P single bond and bridged by two Na atoms. In addition, two terminal Na atoms are attached to the P clusters. The Na atoms are also coordinated by two dimethoxy­ethane mol­ecules, resulting in distorted cis-NaP2O4 octa­hedra.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807010100/hb2311sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807010100/hb2311Isup2.hkl
Contains datablock I

CCDC reference: 643006

Key indicators

  • Single-crystal X-ray study
  • T = 173 K
  • Mean [sigma](C-C) = 0.014 Å
  • R factor = 0.068
  • wR factor = 0.122
  • Data-to-parameter ratio = 18.7

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT328_ALERT_2_B Check for Possibly Missing H on sp3? Phosphor .. P7 PLAT340_ALERT_3_B Low Bond Precision on C-C bonds (x 1000) Ang ... 15
Alert level C PLAT026_ALERT_3_C Ratio Observed / Unique Reflections too Low .... 46 Perc. PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.85 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.57 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C3 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C13 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C14 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for Na1 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for O12 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for O15 PLAT322_ALERT_2_C Check Hybridisation of P1 in Main Residue . ? PLAT322_ALERT_2_C Check Hybridisation of P2 in Main Residue . ? PLAT322_ALERT_2_C Check Hybridisation of P6 in Main Residue . ? PLAT360_ALERT_2_C Short C(sp3)-C(sp3) Bond C3 - C4 ... 1.42 Ang. PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 205 P3 -NA2 -O35 -C36 32.00 2.00 3.766 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 210 P3 -NA2 -O35 -C34 166.20 1.70 3.766 1.555 1.555 1.555
0 ALERT level A = In general: serious problem 2 ALERT level B = Potentially serious problem 15 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 12 ALERT type 2 Indicator that the structure model may be wrong or deficient 3 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: X-AREA (Stoe & Cie, 2001); cell refinement: X-AREA; data reduction: X-AREA; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP in SHELXTL-Plus (Sheldrick, 1991); software used to prepare material for publication: SHELXL97 and PLATON.

4-3,3'-Bi[tricyclo[2.2.1.02,6]heptaphosphane](4-)}tetrakis[bis(1,2- dimethoxyethane)sodium(I)] top
Crystal data top
[Na4(P14)(C4H10O2)8]F(000) = 1308
Mr = 1246.50Dx = 1.300 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 6420 reflections
a = 12.444 (2) Åθ = 3.5–25.2°
b = 20.264 (3) ŵ = 0.45 mm1
c = 12.874 (2) ÅT = 173 K
β = 101.32 (1)°Cut needle, yellow
V = 3183.2 (9) Å30.26 × 0.14 × 0.13 mm
Z = 2
Data collection top
Stoe IPDSII two-circle
diffractometer
5581 independent reflections
Radiation source: fine-focus sealed tube2557 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.090
ω scansθmax = 25.1°, θmin = 3.5°
Absorption correction: multi-scan
(MULABS; Spek, 2003; Blessing, 1995)
h = 1414
Tmin = 0.892, Tmax = 0.944k = 2424
9106 measured reflectionsl = 1511
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.068Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.122H-atom parameters constrained
S = 0.89 w = 1/[σ2(Fo2) + (0.02P)2]
where P = (Fo2 + 2Fc2)/3
5581 reflections(Δ/σ)max < 0.001
298 parametersΔρmax = 0.32 e Å3
0 restraintsΔρmin = 0.29 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Na10.71143 (18)0.37461 (13)0.1408 (2)0.0496 (7)
Na20.83111 (16)0.60389 (11)0.6357 (2)0.0428 (6)
P10.93175 (13)0.58077 (8)0.34493 (17)0.0462 (4)
P20.93465 (13)0.51308 (10)0.20687 (16)0.0525 (5)
P30.93641 (12)0.41337 (9)0.26492 (16)0.0453 (5)
P40.83808 (12)0.42619 (8)0.38504 (14)0.0379 (4)
P50.91180 (11)0.51427 (9)0.47426 (14)0.0364 (4)
P60.77460 (13)0.55614 (9)0.23084 (17)0.0510 (5)
P70.69360 (11)0.47926 (9)0.30377 (15)0.0430 (4)
C10.8413 (7)0.2517 (5)0.0411 (10)0.114 (4)
H1A0.83270.28350.01720.171*
H1B0.83420.20670.01240.171*
H1C0.91370.25710.08660.171*
O20.7599 (6)0.2627 (3)0.1008 (7)0.100 (2)
C30.7613 (8)0.2214 (5)0.1838 (13)0.131 (6)
H3A0.83320.22610.23230.158*
H3B0.75690.17560.15640.158*
C40.6786 (11)0.2293 (5)0.2443 (10)0.112 (4)
H4A0.61810.19860.21570.135*
H4B0.70930.21510.31770.135*
O50.6363 (5)0.2884 (3)0.2487 (7)0.102 (2)
C60.5682 (8)0.2984 (5)0.3196 (9)0.104 (3)
H6A0.54170.34410.31420.157*
H6B0.60870.29010.39170.157*
H6C0.50560.26820.30340.157*
C110.9508 (7)0.7460 (5)0.6092 (11)0.147 (6)
H11A0.98060.72350.55370.221*
H11B0.99740.73680.67830.221*
H11C0.94880.79370.59620.221*
O120.8432 (4)0.7227 (3)0.6084 (6)0.0789 (18)
C130.7897 (10)0.7520 (5)0.6842 (12)0.125 (5)
H13A0.70960.74620.66030.150*
H13B0.80490.80000.68640.150*
C140.8222 (9)0.7248 (6)0.7944 (11)0.119 (5)
H14A0.90240.72920.81930.143*
H14B0.78520.74980.84340.143*
O150.7924 (4)0.6587 (3)0.7937 (5)0.0669 (16)
C160.8341 (7)0.6277 (5)0.8928 (8)0.090 (3)
H16A0.81210.58120.88930.135*
H16B0.80470.64990.94890.135*
H16C0.91430.63070.90840.135*
C210.4411 (5)0.3576 (4)0.0220 (8)0.083 (3)
H21A0.44260.33910.09260.125*
H21B0.43490.32170.02990.125*
H21C0.37810.38720.00310.125*
O220.5388 (3)0.3932 (3)0.0222 (4)0.0618 (14)
C230.5451 (5)0.4220 (4)0.0758 (6)0.066 (2)
H23A0.48640.45530.09500.079*
H23B0.53490.38780.13170.079*
C240.6527 (6)0.4535 (4)0.0682 (7)0.069 (2)
H24A0.65650.47480.13650.083*
H24B0.66200.48820.01290.083*
O250.7376 (3)0.4069 (3)0.0429 (4)0.0662 (15)
C260.8425 (6)0.4307 (5)0.0602 (7)0.087 (3)
H26A0.89780.39600.04150.130*
H26B0.86440.46960.01580.130*
H26C0.83640.44260.13490.130*
C310.7259 (5)0.4541 (3)0.6451 (7)0.057 (2)
H31A0.80260.43980.66260.085*
H31B0.70100.45420.56800.085*
H31C0.68050.42360.67700.085*
O320.7166 (3)0.5186 (2)0.6851 (4)0.0451 (11)
C330.6065 (4)0.5427 (3)0.6607 (6)0.052 (2)
H33A0.59750.57740.71250.062*
H33B0.55570.50630.66820.062*
C340.5759 (4)0.5706 (3)0.5512 (6)0.0516 (19)
H34A0.58760.53730.49830.062*
H34B0.49770.58360.53600.062*
O350.6438 (3)0.6271 (2)0.5459 (4)0.0516 (13)
C360.6216 (6)0.6576 (4)0.4445 (7)0.070 (2)
H36A0.67000.69570.44460.104*
H36B0.54510.67210.42810.104*
H36C0.63460.62580.39080.104*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Na10.0419 (12)0.0569 (16)0.0454 (19)0.0001 (12)0.0029 (11)0.0058 (14)
Na20.0320 (11)0.0456 (14)0.0496 (18)0.0006 (10)0.0044 (11)0.0067 (13)
P10.0433 (8)0.0382 (9)0.0508 (12)0.0062 (8)0.0062 (8)0.0030 (10)
P20.0420 (9)0.0753 (13)0.0388 (12)0.0129 (9)0.0045 (8)0.0016 (11)
P30.0298 (7)0.0562 (11)0.0469 (12)0.0055 (7)0.0000 (7)0.0164 (10)
P40.0352 (7)0.0387 (9)0.0376 (11)0.0025 (7)0.0016 (7)0.0006 (8)
P50.0304 (7)0.0425 (9)0.0349 (10)0.0018 (7)0.0029 (7)0.0048 (9)
P60.0462 (9)0.0468 (10)0.0520 (13)0.0042 (8)0.0098 (9)0.0065 (10)
P70.0285 (7)0.0518 (10)0.0462 (12)0.0025 (7)0.0011 (7)0.0064 (10)
C10.079 (6)0.106 (8)0.154 (13)0.007 (6)0.015 (7)0.034 (8)
O20.121 (5)0.071 (4)0.113 (7)0.013 (4)0.036 (5)0.015 (4)
C30.086 (7)0.070 (7)0.238 (19)0.002 (6)0.033 (9)0.051 (9)
C40.142 (10)0.080 (8)0.115 (11)0.008 (7)0.027 (8)0.004 (7)
O50.116 (5)0.066 (4)0.137 (7)0.021 (4)0.057 (5)0.032 (4)
C60.108 (7)0.109 (8)0.101 (10)0.008 (6)0.030 (7)0.027 (7)
C110.087 (7)0.140 (10)0.190 (14)0.057 (7)0.036 (7)0.113 (9)
O120.074 (3)0.054 (3)0.100 (5)0.010 (3)0.005 (3)0.007 (3)
C130.139 (10)0.052 (6)0.162 (15)0.020 (6)0.021 (10)0.033 (8)
C140.115 (8)0.111 (9)0.131 (13)0.005 (7)0.025 (8)0.077 (9)
O150.056 (3)0.070 (4)0.077 (5)0.005 (3)0.018 (3)0.030 (3)
C160.075 (5)0.140 (9)0.055 (7)0.011 (6)0.012 (5)0.021 (7)
C210.046 (4)0.094 (6)0.102 (8)0.015 (4)0.003 (4)0.015 (6)
O220.045 (2)0.080 (3)0.054 (4)0.009 (2)0.007 (2)0.010 (3)
C230.050 (4)0.095 (6)0.045 (5)0.019 (4)0.008 (3)0.005 (5)
C240.083 (5)0.074 (5)0.053 (6)0.010 (4)0.018 (4)0.017 (5)
O250.049 (3)0.084 (4)0.063 (4)0.001 (3)0.005 (2)0.008 (3)
C260.057 (4)0.144 (9)0.055 (6)0.015 (5)0.001 (4)0.001 (6)
C310.050 (4)0.051 (4)0.069 (6)0.008 (3)0.012 (4)0.001 (4)
O320.034 (2)0.050 (3)0.050 (3)0.003 (2)0.0066 (19)0.007 (3)
C330.032 (3)0.061 (4)0.063 (6)0.007 (3)0.009 (3)0.017 (4)
C340.029 (3)0.065 (5)0.057 (5)0.005 (3)0.002 (3)0.006 (4)
O350.041 (2)0.053 (3)0.056 (4)0.004 (2)0.001 (2)0.003 (3)
C360.073 (5)0.073 (5)0.056 (6)0.005 (4)0.005 (4)0.009 (5)
Geometric parameters (Å, º) top
Na1—O222.408 (5)O12—C131.415 (14)
Na1—O22.428 (7)C13—C141.502 (16)
Na1—O52.522 (7)C13—H13A0.9900
Na1—O252.536 (6)C13—H13B0.9900
Na1—P73.022 (3)C14—O151.390 (11)
Na1—P33.042 (3)C14—H14A0.9900
Na2—O322.405 (5)C14—H14B0.9900
Na2—O352.436 (5)O15—C161.425 (10)
Na2—O122.443 (6)C16—H16A0.9800
Na2—O152.447 (6)C16—H16B0.9800
Na2—P3i2.945 (3)C16—H16C0.9800
Na2—P53.073 (3)C21—O221.415 (7)
P1—P52.194 (3)C21—H21A0.9800
P1—P22.251 (3)C21—H21B0.9800
P1—P62.259 (2)C21—H21C0.9800
P2—P32.153 (3)O22—C231.406 (8)
P2—P62.250 (3)C23—C241.468 (9)
P3—P42.168 (2)C23—H23A0.9900
P4—P72.178 (2)C23—H23B0.9900
P4—P52.221 (2)C24—O251.408 (8)
P5—P5i2.241 (3)C24—H24A0.9900
P6—P72.167 (3)C24—H24B0.9900
P3—Na2i2.945 (3)O25—C261.449 (8)
C1—O21.404 (11)C26—H26A0.9800
C1—H1A0.9800C26—H26B0.9800
C1—H1B0.9800C26—H26C0.9800
C1—H1C0.9800C31—O321.418 (7)
O2—C31.354 (13)C31—H31A0.9800
C3—C41.416 (14)C31—H31B0.9800
C3—H3A0.9900C31—H31C0.9800
C3—H3B0.9900O32—C331.430 (6)
C4—O51.315 (11)C33—C341.497 (10)
C4—H4A0.9900C33—H33A0.9900
C4—H4B0.9900C33—H33B0.9900
O5—C61.377 (11)C34—O351.432 (7)
C6—H6A0.9800C34—H34A0.9900
C6—H6B0.9800C34—H34B0.9900
C6—H6C0.9800O35—C361.422 (9)
C11—O121.418 (9)C36—H36A0.9800
C11—H11A0.9800C36—H36B0.9800
C11—H11B0.9800C36—H36C0.9800
C11—H11C0.9800
O22—Na1—O2103.9 (2)H11A—C11—H11B109.5
O22—Na1—O594.4 (2)O12—C11—H11C109.5
O2—Na1—O566.7 (3)H11A—C11—H11C109.5
O22—Na1—O2568.28 (17)H11B—C11—H11C109.5
O2—Na1—O2587.7 (3)C11—O12—C13115.3 (9)
O5—Na1—O25145.2 (2)C11—O12—Na2114.3 (5)
O22—Na1—P798.77 (15)C13—O12—Na2105.3 (6)
O2—Na1—P7149.1 (2)O12—C13—C14114.9 (9)
O5—Na1—P791.0 (2)O12—C13—H13A108.5
O25—Na1—P7120.47 (16)C14—C13—H13A108.5
O22—Na1—P3155.08 (17)O12—C13—H13B108.5
O2—Na1—P396.39 (19)C14—C13—H13B108.5
O5—Na1—P3107.0 (2)H13A—C13—H13B107.5
O25—Na1—P398.61 (13)O15—C14—C13109.0 (9)
P7—Na1—P368.87 (7)O15—C14—H14A109.9
O32—Na2—O3572.70 (15)C13—C14—H14A109.9
O32—Na2—O12143.5 (2)O15—C14—H14B109.9
O35—Na2—O1279.73 (18)C13—C14—H14B109.9
O32—Na2—O1583.27 (18)H14A—C14—H14B108.3
O35—Na2—O1588.90 (18)C14—O15—C16111.6 (8)
O12—Na2—O1572.5 (2)C14—O15—Na2110.3 (6)
O32—Na2—P3i112.48 (14)C16—O15—Na2116.6 (5)
O35—Na2—P3i174.82 (16)O15—C16—H16A109.5
O12—Na2—P3i95.54 (15)O15—C16—H16B109.5
O15—Na2—P3i91.70 (15)H16A—C16—H16B109.5
O32—Na2—P592.49 (13)O15—C16—H16C109.5
O35—Na2—P5101.67 (15)H16A—C16—H16C109.5
O12—Na2—P5116.6 (2)H16B—C16—H16C109.5
O15—Na2—P5166.94 (18)O22—C21—H21A109.5
P3i—Na2—P578.47 (7)O22—C21—H21B109.5
P5—P1—P2104.28 (10)H21A—C21—H21B109.5
P5—P1—P698.35 (9)O22—C21—H21C109.5
P2—P1—P659.87 (8)H21A—C21—H21C109.5
P3—P2—P6105.38 (9)H21B—C21—H21C109.5
P3—P2—P1107.36 (11)C23—O22—C21114.2 (6)
P6—P2—P160.24 (8)C23—O22—Na1115.7 (4)
P2—P3—P499.58 (10)C21—O22—Na1125.5 (5)
P2—P3—Na2i101.80 (8)O22—C23—C24109.3 (6)
P4—P3—Na2i110.38 (10)O22—C23—H23A109.8
P2—P3—Na196.57 (9)C24—C23—H23A109.8
P4—P3—Na179.36 (8)O22—C23—H23B109.8
Na2i—P3—Na1157.19 (10)C24—C23—H23B109.8
P3—P4—P7104.17 (10)H23A—C23—H23B108.3
P3—P4—P5103.39 (9)O25—C24—C23110.9 (6)
P7—P4—P594.01 (9)O25—C24—H24A109.5
P1—P5—P4101.41 (10)C23—C24—H24A109.5
P1—P5—P5i97.63 (11)O25—C24—H24B109.5
P4—P5—P5i103.11 (11)C23—C24—H24B109.5
P1—P5—Na2104.54 (10)H24A—C24—H24B108.0
P4—P5—Na2131.91 (8)C24—O25—C26113.5 (6)
P5i—P5—Na2112.56 (11)C24—O25—Na199.2 (4)
P7—P6—P2106.27 (10)C26—O25—Na1120.9 (4)
P7—P6—P1107.10 (10)O25—C26—H26A109.5
P2—P6—P159.89 (8)O25—C26—H26B109.5
P6—P7—P498.78 (8)H26A—C26—H26B109.5
P6—P7—Na195.74 (10)O25—C26—H26C109.5
P4—P7—Na179.68 (8)H26A—C26—H26C109.5
O2—C1—H1A109.5H26B—C26—H26C109.5
O2—C1—H1B109.5O32—C31—H31A109.5
H1A—C1—H1B109.5O32—C31—H31B109.5
O2—C1—H1C109.5H31A—C31—H31B109.5
H1A—C1—H1C109.5O32—C31—H31C109.5
H1B—C1—H1C109.5H31A—C31—H31C109.5
C3—O2—C1115.8 (9)H31B—C31—H31C109.5
C3—O2—Na1112.0 (7)C31—O32—C33112.3 (5)
C1—O2—Na1120.0 (6)C31—O32—Na2118.1 (4)
O2—C3—C4117.8 (10)C33—O32—Na2106.7 (4)
O2—C3—H3A107.9O32—C33—C34113.1 (6)
C4—C3—H3A107.9O32—C33—H33A109.0
O2—C3—H3B107.9C34—C33—H33A109.0
C4—C3—H3B107.9O32—C33—H33B109.0
H3A—C3—H3B107.2C34—C33—H33B109.0
O5—C4—C3117.8 (10)H33A—C33—H33B107.8
O5—C4—H4A107.9O35—C34—C33107.6 (5)
C3—C4—H4A107.9O35—C34—H34A110.2
O5—C4—H4B107.9C33—C34—H34A110.2
C3—C4—H4B107.9O35—C34—H34B110.2
H4A—C4—H4B107.2C33—C34—H34B110.2
C4—O5—C6117.8 (9)H34A—C34—H34B108.5
C4—O5—Na1114.4 (7)C36—O35—C34112.4 (5)
C6—O5—Na1127.3 (6)C36—O35—Na2121.0 (4)
O5—C6—H6A109.5C34—O35—Na2110.0 (4)
O5—C6—H6B109.5O35—C36—H36A109.5
H6A—C6—H6B109.5O35—C36—H36B109.5
O5—C6—H6C109.5H36A—C36—H36B109.5
H6A—C6—H6C109.5O35—C36—H36C109.5
H6B—C6—H6C109.5H36A—C36—H36C109.5
O12—C11—H11A109.5H36B—C36—H36C109.5
O12—C11—H11B109.5
P5—P1—P2—P36.66 (11)O22—Na1—O2—C3114.9 (7)
P6—P1—P2—P398.13 (10)O5—Na1—O2—C326.0 (7)
P5—P1—P2—P691.46 (9)O25—Na1—O2—C3178.1 (7)
P6—P2—P3—P429.54 (11)P7—Na1—O2—C321.0 (9)
P1—P2—P3—P433.50 (10)P3—Na1—O2—C379.7 (7)
P6—P2—P3—Na2i142.87 (10)P4—Na1—O2—C343.3 (7)
P1—P2—P3—Na2i79.83 (10)O22—Na1—O2—C1104.2 (7)
P6—P2—P3—Na150.73 (11)O5—Na1—O2—C1166.9 (8)
P1—P2—P3—Na1113.77 (9)O25—Na1—O2—C137.3 (7)
O22—Na1—P3—P22.6 (4)P7—Na1—O2—C1119.9 (7)
O2—Na1—P3—P2141.9 (2)P3—Na1—O2—C161.1 (7)
O5—Na1—P3—P2150.6 (2)P4—Na1—O2—C197.6 (7)
O25—Na1—P3—P253.20 (16)C1—O2—C3—C4178.0 (10)
P7—Na1—P3—P266.22 (9)Na1—O2—C3—C439.3 (13)
P4—Na1—P3—P298.56 (10)O2—C3—C4—O528.1 (19)
O22—Na1—P3—P496.0 (4)C3—C4—O5—C6170.6 (11)
O2—Na1—P3—P4119.6 (2)C3—C4—O5—Na11.7 (15)
O5—Na1—P3—P452.1 (2)O22—Na1—O5—C4116.0 (8)
O25—Na1—P3—P4151.76 (15)O2—Na1—O5—C412.8 (8)
P7—Na1—P3—P432.33 (7)O25—Na1—O5—C458.7 (9)
O22—Na1—P3—Na2i146.2 (4)P7—Na1—O5—C4145.1 (8)
O2—Na1—P3—Na2i1.7 (4)P3—Na1—O5—C476.9 (8)
O5—Na1—P3—Na2i65.8 (3)P4—Na1—O5—C4106.9 (8)
O25—Na1—P3—Na2i90.4 (3)O22—Na1—O5—C672.5 (8)
P7—Na1—P3—Na2i150.2 (3)O2—Na1—O5—C6175.8 (9)
P4—Na1—P3—Na2i117.9 (3)O25—Na1—O5—C6129.9 (8)
P2—P3—P4—P749.42 (10)P7—Na1—O5—C626.3 (8)
Na2i—P3—P4—P7155.91 (9)P3—Na1—O5—C694.5 (8)
Na1—P3—P4—P745.54 (9)P4—Na1—O5—C664.5 (8)
P2—P3—P4—P548.30 (10)O32—Na2—O12—C11161.5 (7)
Na2i—P3—P4—P558.19 (11)O35—Na2—O12—C11157.3 (8)
Na1—P3—P4—P5143.25 (9)O15—Na2—O12—C11110.6 (7)
P2—P3—P4—Na194.95 (9)P3i—Na2—O12—C1120.6 (7)
Na2i—P3—P4—Na1158.56 (11)P5—Na2—O12—C1159.3 (8)
O22—Na1—P4—P3141.9 (2)O32—Na2—O12—C1333.9 (8)
O2—Na1—P4—P370.1 (2)O35—Na2—O12—C1375.2 (6)
O5—Na1—P4—P3130.35 (18)O15—Na2—O12—C1316.9 (6)
O25—Na1—P4—P338.70 (19)P3i—Na2—O12—C13107.0 (6)
P7—Na1—P4—P3127.82 (11)P5—Na2—O12—C13173.2 (6)
O22—Na1—P4—P714.1 (2)C11—O12—C13—C1479.8 (11)
O2—Na1—P4—P7162.0 (2)Na2—O12—C13—C1447.1 (10)
O5—Na1—P4—P7101.83 (17)O12—C13—C14—O1563.4 (12)
O25—Na1—P4—P789.1 (2)C13—C14—O15—C16172.1 (8)
P3—Na1—P4—P7127.82 (11)C13—C14—O15—Na240.8 (10)
O22—Na1—P4—P567.8 (3)O32—Na2—O15—C14166.0 (7)
O2—Na1—P4—P5144.3 (2)O35—Na2—O15—C1493.3 (6)
O5—Na1—P4—P5155.47 (19)O12—Na2—O15—C1413.7 (6)
O25—Na1—P4—P535.5 (3)P3i—Na2—O15—C1481.6 (6)
P7—Na1—P4—P553.64 (13)P5—Na2—O15—C14122.4 (8)
P3—Na1—P4—P574.18 (14)O32—Na2—O15—C1665.3 (5)
P2—P1—P5—P422.46 (10)O35—Na2—O15—C16138.1 (5)
P6—P1—P5—P438.45 (10)O12—Na2—O15—C16142.4 (5)
P2—P1—P5—P5i82.64 (12)P3i—Na2—O15—C1647.1 (5)
P6—P1—P5—P5i143.55 (11)P5—Na2—O15—C166.3 (10)
P2—P1—P5—Na2161.61 (8)O2—Na1—O22—C2392.2 (6)
P6—P1—P5—Na2100.70 (9)O5—Na1—O22—C23159.2 (5)
P3—P4—P5—P144.73 (10)O25—Na1—O22—C2310.4 (5)
P7—P4—P5—P160.87 (10)P7—Na1—O22—C23109.0 (5)
Na1—P4—P5—P115.87 (16)P3—Na1—O22—C2351.3 (7)
P3—P4—P5—P5i55.99 (14)O2—Na1—O22—C2162.3 (7)
P7—P4—P5—P5i161.60 (12)O5—Na1—O22—C214.7 (6)
Na1—P4—P5—P5i116.59 (14)O25—Na1—O22—C21144.1 (6)
P3—P4—P5—Na2166.42 (11)P7—Na1—O22—C2196.5 (6)
P7—P4—P5—Na260.81 (14)P3—Na1—O22—C21154.2 (6)
Na1—P4—P5—Na2105.82 (16)C21—O22—C23—C24176.0 (6)
O32—Na2—P5—P1145.08 (13)Na1—O22—C23—C2418.6 (8)
O35—Na2—P5—P172.23 (15)O22—C23—C24—O2560.6 (9)
O12—Na2—P5—P112.01 (18)C23—C24—O25—C26165.3 (7)
O15—Na2—P5—P1144.3 (6)C23—C24—O25—Na165.0 (7)
P3i—Na2—P5—P1102.48 (8)O22—Na1—O25—C2437.4 (4)
O32—Na2—P5—P424.58 (18)O2—Na1—O25—C24143.3 (4)
O35—Na2—P5—P448.26 (19)O5—Na1—O25—C24102.1 (5)
O12—Na2—P5—P4132.51 (18)P7—Na1—O25—C2450.1 (4)
O15—Na2—P5—P495.2 (6)P3—Na1—O25—C24120.6 (4)
P3i—Na2—P5—P4137.03 (12)O22—Na1—O25—C26162.1 (6)
O32—Na2—P5—P5i110.08 (15)O2—Na1—O25—C2692.0 (6)
O35—Na2—P5—P5i177.08 (16)O5—Na1—O25—C26133.3 (6)
O12—Na2—P5—P5i92.8 (2)P7—Na1—O25—C2674.6 (6)
O15—Na2—P5—P5i39.4 (7)P3—Na1—O25—C264.1 (6)
P3i—Na2—P5—P5i2.36 (13)P4—Na1—O25—C2627.5 (6)
P3—P2—P6—P70.84 (14)O35—Na2—O32—C31109.7 (5)
P1—P2—P6—P7100.65 (11)O12—Na2—O32—C31152.5 (5)
P3—P2—P6—P1101.49 (11)O15—Na2—O32—C31159.3 (5)
P5—P1—P6—P72.49 (13)P3i—Na2—O32—C3170.3 (5)
P2—P1—P6—P799.23 (11)P5—Na2—O32—C318.3 (5)
P5—P1—P6—P2101.72 (10)O35—Na2—O32—C3317.7 (4)
P2—P6—P7—P428.01 (13)O12—Na2—O32—C3325.0 (6)
P1—P6—P7—P434.80 (12)O15—Na2—O32—C3373.2 (4)
P2—P6—P7—Na152.39 (11)P3i—Na2—O32—C33162.3 (4)
P1—P6—P7—Na1115.20 (10)P5—Na2—O32—C33119.2 (4)
P3—P4—P7—P648.41 (11)C31—O32—C33—C3481.9 (7)
P5—P4—P7—P656.49 (11)Na2—O32—C33—C3448.9 (6)
Na1—P4—P7—P694.28 (10)O32—C33—C34—O3564.1 (7)
P3—P4—P7—Na145.87 (9)C33—C34—O35—C36179.9 (6)
P5—P4—P7—Na1150.77 (9)C33—C34—O35—Na241.9 (6)
O22—Na1—P7—P691.75 (15)O32—Na2—O35—C36147.5 (5)
O2—Na1—P7—P6131.4 (4)O12—Na2—O35—C3656.8 (5)
O5—Na1—P7—P6173.61 (17)O15—Na2—O35—C36129.2 (5)
O25—Na1—P7—P621.85 (15)P3i—Na2—O35—C3632 (2)
P3—Na1—P7—P665.80 (8)P5—Na2—O35—C3658.5 (5)
P4—Na1—P7—P697.92 (8)O32—Na2—O35—C3413.8 (4)
O22—Na1—P7—P4170.34 (16)O12—Na2—O35—C34169.5 (5)
O2—Na1—P7—P433.5 (4)O15—Na2—O35—C3497.1 (4)
O5—Na1—P7—P475.70 (18)P3i—Na2—O35—C34166.2 (17)
O25—Na1—P7—P4119.76 (15)P5—Na2—O35—C3475.2 (4)
P3—Na1—P7—P432.12 (7)
Symmetry code: (i) x+2, y+1, z+1.
 

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