Acta Cryst. (2007). E63, m1147-m1148  [ doi:10.1107/S1600536807012469 ]

Bis(tetraphenylphosphonium) tris(2-thioxo-1,3-dithiole-4,5-dithiolato)stannate(IV) at 293 K

Y.-L. Wang, Y.-J. Wang, J. Yao, X.-T. Zhao and R.-H. Wang

Abstract: The title compound, (C₂₄H₂₀P)₂[Sn(C₃S₅)₃], whose structure has been previously reported in the space group P at 120 K [de Assis, Chohan, Howie, Khan, Low, Spencer, Wardell & Wardell (1999), Polyhedron, 18, 3533-3544], has been crystallized in the space group C2/c and its structure has been determined at 293 K. The [Sn(C₃S₅)₃]^2- anion possesses C₂ symmetry, with the Sn^IV atom and one C=S group lying on the twofold rotation axis. The crystal packing is stabilized by C-HS hydrogen bonds.

Online 28 March 2007

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