Bis(tetra­phenyl­phospho­nium) tris­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)stannate(IV) at 293 K

Wang, Y.-L.; Wang, Y.-J.; Yao, J.; Zhao, X.-T.; Wang, R.-H.

doi:10.1107/S1600536807012469

Bis(tetraphenylphosphonium) tris(2-thioxo-1,3-dithiole-4,5-dithiolato)stannate(IV) at 293 K

Y.-L. Wang, Y.-J. Wang, J. Yao, X.-T. Zhao and R.-H. Wang

The title compound, (C₂₄H₂₀P)₂[Sn(C₃S₅)₃], whose structure has been previously reported in the space group P $\overline{1}$ at 120 K [de Assis, Chohan, Howie, Khan, Low, Spencer, Wardell & Wardell (1999), Polyhedron, 18, 3533–3544], has been crystallized in the space group C2/c and its structure has been determined at 293 K. The [Sn(C₃S₅)₃]²⁻ anion possesses C₂ symmetry, with the Sn^IV atom and one C=S group lying on the twofold rotation axis. The crystal packing is stabilized by C—H

S hydrogen bonds.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807012469/hy2045sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536807012469/hy2045Isup2.hkl Contains datablock I

CCDC reference: 643036

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.004 Å
R factor = 0.024
wR factor = 0.065
Data-to-parameter ratio = 20.4

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Sn1    -   S4      ..      11.78 su

Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Sn1    -   S5      ..       6.13 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Sn1    -   S6      ..       9.87 su
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C5

Alert level G
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
   4 ALERT level C = Check and explain
   2 ALERT level G = General alerts; check

   3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: APEX2 (Bruker, 2005); cell refinement: APEX2; data reduction: APEX2; program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

Bis(tetraphenylphosphonium) tris(2-thioxo-1,3-dithiole-4,5-dithiolato)stannate(IV) top

Crystal data top

(C₂₄H₂₀P)₂[Sn(C₃S₅)₃]	F(000) = 2808
M_r = 1386.42	D_x = 1.541 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 8898 reflections
a = 24.7352 (6) Å	θ = 2.5–27.6°
b = 14.7677 (4) Å	µ = 1.04 mm⁻¹
c = 19.6210 (4) Å	T = 293 K
β = 123.532 (2)°	Prism, purple–red
V = 5974.4 (3) Å³	0.36 × 0.12 × 0.11 mm
Z = 4

Data collection top

Bruker APEXII CCD area-detector diffractometer	6936 independent reflections
Radiation source: fine-focus sealed tube	6060 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.024
φ and ω scans	θ_max = 27.6°, θ_min = 1.7°
Absorption correction: multi-scan (SADABS; Bruker, 2005)	h = −32→30
T_min = 0.706, T_max = 0.895	k = −19→19
40822 measured reflections	l = −24→25

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.024	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.065	H-atom parameters constrained
S = 1.04	w = 1/[σ²(F_o²) + (0.0318P)² + 4.1278P] where P = (F_o² + 2F_c²)/3
6936 reflections	(Δ/σ)_max = 0.001
340 parameters	Δρ_max = 0.39 e Å⁻³
0 restraints	Δρ_min = −0.42 e Å⁻³

Special details top

Experimental. Along chemical bond of Sn1 and S4, the magnitude of the components of the anisotropic displacement parameters has larger difference. There was no significant improvement for this effect in the refinement using DELU etc instruction in the SHELXTL97 program as so as redo absorption correction for the original data.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
C1	0.36637 (9)	−0.08672 (12)	0.08963 (11)	0.0428 (4)
C2	0.39171 (8)	0.08716 (11)	0.11338 (10)	0.0361 (4)
C3	0.44805 (8)	0.04790 (11)	0.13238 (10)	0.0366 (4)
C4	0.49057 (9)	0.43890 (12)	0.27602 (11)	0.0411 (4)
C5	0.5000	0.61163 (19)	0.2500	0.0594 (8)
S1	0.33102 (3)	−0.18687 (4)	0.06668 (4)	0.06359 (16)
S2	0.32684 (2)	0.01314 (3)	0.08100 (3)	0.04214 (10)
S3	0.44663 (2)	−0.06984 (3)	0.12443 (3)	0.04594 (11)
S4	0.38207 (2)	0.20063 (3)	0.12721 (3)	0.04336 (11)
S5	0.52109 (2)	0.10405 (3)	0.17151 (3)	0.04444 (11)
S6	0.47533 (3)	0.34592 (3)	0.31770 (3)	0.04668 (11)
S7	0.48042 (3)	0.54604 (4)	0.30613 (4)	0.05676 (14)
S8	0.5000	0.72282 (6)	0.2500	0.0977 (4)
Sn1	0.5000	0.221483 (10)	0.2500	0.03296 (5)
C17	0.87001 (11)	0.45376 (15)	0.40971 (12)	0.0556 (5)
H17	0.8679	0.4769	0.4523	0.067*
C18	0.72469 (9)	0.61019 (13)	0.20875 (11)	0.0435 (4)
C19	0.66022 (10)	0.58471 (16)	0.16670 (13)	0.0549 (5)
H19	0.6449	0.5508	0.1926	0.066*
C20	0.61854 (12)	0.61020 (18)	0.08539 (14)	0.0655 (6)
H20	0.5751	0.5932	0.0568	0.079*
C21	0.64094 (13)	0.66017 (17)	0.04721 (13)	0.0668 (7)
H21	0.6125	0.6779	−0.0069	0.080*
C22	0.70506 (13)	0.68421 (18)	0.08817 (14)	0.0682 (7)
H22	0.7201	0.7171	0.0614	0.082*
C23	0.74761 (12)	0.65963 (16)	0.16941 (13)	0.0596 (6)
H23	0.7911	0.6761	0.1973	0.071*
C24	0.73080 (9)	0.54458 (12)	0.35312 (10)	0.0386 (4)
C25	0.71628 (11)	0.45288 (14)	0.34807 (14)	0.0560 (5)
H25	0.7323	0.4121	0.3273	0.067*
C26	0.67789 (12)	0.42305 (16)	0.37420 (16)	0.0677 (7)
H26	0.6683	0.3617	0.3715	0.081*
C27	0.65391 (11)	0.48258 (18)	0.40383 (14)	0.0634 (6)
H27	0.6281	0.4615	0.4214	0.076*
C28	0.66709 (11)	0.57297 (17)	0.40822 (14)	0.0589 (5)
H28	0.6501	0.6132	0.4281	0.071*
C29	0.70608 (10)	0.60430 (14)	0.38275 (12)	0.0471 (4)
H29	0.7154	0.6657	0.3858	0.057*
P1	0.77855 (2)	0.58323 (3)	0.31547 (3)	0.03753 (10)
C6	0.82272 (9)	0.68477 (12)	0.36579 (11)	0.0402 (4)
C7	0.78909 (11)	0.76564 (14)	0.34992 (15)	0.0565 (5)
H7	0.7444	0.7672	0.3128	0.068*
C8	0.82229 (12)	0.84360 (15)	0.38947 (16)	0.0694 (7)
H8	0.7997	0.8975	0.3799	0.083*
C9	0.88839 (13)	0.84229 (17)	0.44281 (16)	0.0698 (7)
H9	0.9105	0.8952	0.4691	0.084*
C10	0.92177 (12)	0.76317 (17)	0.45740 (16)	0.0687 (7)
H10	0.9667	0.7628	0.4933	0.082*
C11	0.88956 (10)	0.68385 (15)	0.41949 (13)	0.0519 (5)
H11	0.9126	0.6302	0.4299	0.062*
C12	0.83270 (9)	0.49259 (13)	0.33190 (11)	0.0412 (4)
C13	0.83656 (9)	0.45780 (14)	0.26932 (11)	0.0459 (4)
H13	0.8123	0.4835	0.2174	0.055*
C14	0.87663 (11)	0.38466 (15)	0.28414 (13)	0.0549 (5)
H14	0.8790	0.3610	0.2420	0.066*
C15	0.91276 (11)	0.34696 (15)	0.36048 (14)	0.0564 (5)
H15	0.9395	0.2977	0.3698	0.068*
C16	0.90980 (12)	0.38145 (16)	0.42344 (14)	0.0622 (6)
H16	0.9347	0.3559	0.4753	0.075*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.0501 (10)	0.0392 (9)	0.0352 (8)	−0.0051 (8)	0.0211 (8)	−0.0015 (7)
C2	0.0380 (9)	0.0342 (8)	0.0314 (8)	−0.0024 (7)	0.0163 (7)	−0.0029 (6)
C3	0.0398 (9)	0.0345 (8)	0.0347 (8)	−0.0015 (7)	0.0202 (7)	−0.0056 (6)
C4	0.0378 (9)	0.0324 (8)	0.0480 (10)	0.0000 (7)	0.0206 (8)	−0.0039 (7)
C5	0.0439 (15)	0.0349 (14)	0.080 (2)	0.000	0.0217 (15)	0.000
S1	0.0754 (4)	0.0430 (3)	0.0646 (3)	−0.0193 (3)	0.0338 (3)	−0.0051 (2)
S2	0.0382 (2)	0.0443 (2)	0.0400 (2)	−0.00440 (18)	0.01906 (19)	−0.00298 (18)
S3	0.0485 (3)	0.0339 (2)	0.0522 (3)	0.00102 (18)	0.0259 (2)	−0.00564 (19)
S4	0.0385 (2)	0.0349 (2)	0.0426 (2)	0.00669 (17)	0.01353 (19)	−0.00002 (17)
S5	0.0403 (2)	0.0438 (2)	0.0542 (3)	−0.00455 (19)	0.0292 (2)	−0.0126 (2)
S6	0.0627 (3)	0.0394 (2)	0.0488 (3)	0.0008 (2)	0.0376 (2)	−0.00240 (19)
S7	0.0522 (3)	0.0389 (3)	0.0748 (4)	0.0024 (2)	0.0323 (3)	−0.0114 (2)
S8	0.0973 (8)	0.0327 (4)	0.1423 (11)	0.000	0.0532 (8)	0.000
Sn1	0.03601 (9)	0.02899 (8)	0.03119 (8)	0.000	0.01688 (7)	0.000
C17	0.0664 (13)	0.0606 (13)	0.0395 (10)	0.0182 (10)	0.0291 (10)	0.0057 (9)
C18	0.0460 (10)	0.0472 (10)	0.0362 (9)	0.0069 (8)	0.0220 (8)	0.0050 (7)
C19	0.0491 (11)	0.0633 (13)	0.0457 (10)	0.0038 (10)	0.0219 (9)	0.0036 (9)
C20	0.0521 (13)	0.0772 (16)	0.0479 (12)	0.0100 (11)	0.0154 (10)	0.0013 (11)
C21	0.0825 (17)	0.0660 (15)	0.0382 (10)	0.0238 (13)	0.0246 (11)	0.0072 (10)
C22	0.0857 (18)	0.0760 (16)	0.0477 (12)	0.0129 (14)	0.0399 (13)	0.0185 (11)
C23	0.0614 (13)	0.0703 (15)	0.0463 (11)	0.0028 (11)	0.0293 (10)	0.0135 (10)
C24	0.0404 (9)	0.0380 (9)	0.0372 (9)	−0.0031 (7)	0.0213 (7)	0.0030 (7)
C25	0.0638 (13)	0.0409 (11)	0.0653 (13)	−0.0076 (9)	0.0369 (11)	−0.0023 (9)
C26	0.0588 (14)	0.0516 (13)	0.0786 (16)	−0.0168 (11)	0.0291 (13)	0.0124 (11)
C27	0.0431 (11)	0.0836 (17)	0.0606 (13)	−0.0054 (11)	0.0267 (10)	0.0248 (12)
C28	0.0540 (12)	0.0725 (15)	0.0631 (13)	0.0035 (11)	0.0405 (11)	0.0087 (11)
C29	0.0521 (11)	0.0437 (10)	0.0523 (11)	−0.0017 (8)	0.0332 (9)	0.0024 (8)
P1	0.0409 (2)	0.0387 (2)	0.0346 (2)	0.00180 (18)	0.02182 (19)	0.00393 (17)
C6	0.0432 (9)	0.0417 (9)	0.0410 (9)	−0.0012 (7)	0.0266 (8)	0.0056 (7)
C7	0.0468 (11)	0.0424 (11)	0.0710 (14)	0.0014 (9)	0.0268 (10)	0.0093 (10)
C8	0.0705 (16)	0.0384 (11)	0.0890 (17)	0.0013 (10)	0.0376 (14)	0.0063 (11)
C9	0.0711 (16)	0.0503 (13)	0.0780 (16)	−0.0168 (11)	0.0350 (13)	−0.0066 (11)
C10	0.0477 (12)	0.0659 (15)	0.0735 (15)	−0.0098 (11)	0.0214 (11)	−0.0042 (12)
C11	0.0452 (11)	0.0517 (12)	0.0565 (12)	0.0029 (9)	0.0266 (9)	0.0019 (9)
C12	0.0439 (10)	0.0413 (9)	0.0382 (9)	0.0038 (8)	0.0226 (8)	0.0018 (7)
C13	0.0477 (10)	0.0524 (11)	0.0382 (9)	−0.0003 (8)	0.0242 (8)	−0.0001 (8)
C14	0.0604 (13)	0.0576 (12)	0.0555 (12)	0.0017 (10)	0.0375 (11)	−0.0080 (10)
C15	0.0542 (12)	0.0497 (12)	0.0657 (13)	0.0107 (9)	0.0334 (11)	0.0022 (10)
C16	0.0668 (14)	0.0623 (14)	0.0490 (11)	0.0201 (11)	0.0266 (11)	0.0131 (10)

Geometric parameters (Å, º) top

C1—S1	1.6491 (19)	C23—H23	0.9300
C1—S3	1.724 (2)	C24—C29	1.372 (3)
C1—S2	1.725 (2)	C24—C25	1.391 (3)
C2—C3	1.358 (2)	C24—P1	1.7975 (18)
C2—S4	1.7348 (17)	C25—C26	1.377 (3)
C2—S2	1.7455 (17)	C25—H25	0.9300
C3—S5	1.7346 (18)	C26—C27	1.358 (4)
C3—S3	1.7443 (17)	C26—H26	0.9300
C4—C4ⁱ	1.337 (4)	C27—C28	1.365 (3)
C4—S6	1.7427 (19)	C27—H27	0.9300
C4—S7	1.7548 (18)	C28—C29	1.388 (3)
C5—S8	1.642 (3)	C28—H28	0.9300
C5—S7ⁱ	1.7249 (17)	C29—H29	0.9300
C5—S7	1.7249 (17)	P1—C12	1.7924 (19)
S4—Sn1	2.5776 (4)	P1—C6	1.7959 (19)
S5—Sn1	2.5572 (5)	C6—C11	1.385 (3)
S6—Sn1	2.5318 (5)	C6—C7	1.389 (3)
Sn1—S6ⁱ	2.5318 (5)	C7—C8	1.378 (3)
Sn1—S5ⁱ	2.5572 (5)	C7—H7	0.9300
Sn1—S4ⁱ	2.5776 (4)	C8—C9	1.371 (3)
C17—C16	1.374 (3)	C8—H8	0.9300
C17—C12	1.398 (3)	C9—C10	1.367 (4)
C17—H17	0.9300	C9—H9	0.9300
C18—C19	1.383 (3)	C10—C11	1.380 (3)
C18—C23	1.391 (3)	C10—H10	0.9300
C18—P1	1.7989 (18)	C11—H11	0.9300
C19—C20	1.390 (3)	C12—C13	1.382 (3)
C19—H19	0.9300	C13—C14	1.384 (3)
C20—C21	1.368 (4)	C13—H13	0.9300
C20—H20	0.9300	C14—C15	1.369 (3)
C21—C22	1.371 (4)	C14—H14	0.9300
C21—H21	0.9300	C15—C16	1.375 (3)
C22—C23	1.388 (3)	C15—H15	0.9300
C22—H22	0.9300	C16—H16	0.9300

S1—C1—S3	123.97 (12)	C29—C24—C25	119.87 (18)
S1—C1—S2	123.61 (12)	C29—C24—P1	121.20 (14)
S3—C1—S2	112.42 (10)	C25—C24—P1	118.85 (16)
C3—C2—S4	125.34 (13)	C26—C25—C24	119.3 (2)
C3—C2—S2	115.48 (13)	C26—C25—H25	120.4
S4—C2—S2	118.93 (10)	C24—C25—H25	120.4
C2—C3—S5	125.28 (13)	C27—C26—C25	120.4 (2)
C2—C3—S3	115.74 (13)	C27—C26—H26	119.8
S5—C3—S3	118.73 (10)	C25—C26—H26	119.8
C4ⁱ—C4—S6	128.01 (6)	C26—C27—C28	121.0 (2)
C4ⁱ—C4—S7	115.62 (7)	C26—C27—H27	119.5
S6—C4—S7	116.37 (11)	C28—C27—H27	119.5
S8—C5—S7ⁱ	124.16 (8)	C27—C28—C29	119.5 (2)
S8—C5—S7	124.16 (8)	C27—C28—H28	120.3
S7ⁱ—C5—S7	111.67 (16)	C29—C28—H28	120.3
C1—S2—C2	98.19 (9)	C24—C29—C28	119.95 (19)
C1—S3—C3	98.13 (9)	C24—C29—H29	120.0
C2—S4—Sn1	94.54 (6)	C28—C29—H29	120.0
C3—S5—Sn1	94.68 (6)	C12—P1—C6	110.94 (9)
C4—S6—Sn1	98.53 (6)	C12—P1—C24	106.52 (9)
C5—S7—C4	98.54 (10)	C6—P1—C24	112.18 (8)
S6ⁱ—Sn1—S6	86.92 (2)	C12—P1—C18	111.97 (9)
S6ⁱ—Sn1—S5	89.297 (16)	C6—P1—C18	106.83 (9)
S6—Sn1—S5	175.383 (16)	C24—P1—C18	108.45 (9)
S6ⁱ—Sn1—S5ⁱ	175.383 (16)	C11—C6—C7	119.62 (19)
S6—Sn1—S5ⁱ	89.297 (16)	C11—C6—P1	121.20 (15)
S5—Sn1—S5ⁱ	94.60 (2)	C7—C6—P1	119.18 (15)
S6ⁱ—Sn1—S4	94.169 (17)	C8—C7—C6	119.7 (2)
S6—Sn1—S4	95.783 (16)	C8—C7—H7	120.2
S5—Sn1—S4	81.844 (15)	C6—C7—H7	120.2
S5ⁱ—Sn1—S4	88.843 (16)	C9—C8—C7	120.5 (2)
S6ⁱ—Sn1—S4ⁱ	95.783 (16)	C9—C8—H8	119.8
S6—Sn1—S4ⁱ	94.169 (17)	C7—C8—H8	119.8
S5—Sn1—S4ⁱ	88.843 (16)	C10—C9—C8	120.0 (2)
S5ⁱ—Sn1—S4ⁱ	81.844 (15)	C10—C9—H9	120.0
S4—Sn1—S4ⁱ	166.27 (2)	C8—C9—H9	120.0
C16—C17—C12	120.13 (19)	C9—C10—C11	120.7 (2)
C16—C17—H17	119.9	C9—C10—H10	119.6
C12—C17—H17	119.9	C11—C10—H10	119.6
C19—C18—C23	120.07 (18)	C10—C11—C6	119.5 (2)
C19—C18—P1	120.19 (15)	C10—C11—H11	120.2
C23—C18—P1	119.70 (16)	C6—C11—H11	120.2
C18—C19—C20	119.4 (2)	C13—C12—C17	119.33 (18)
C18—C19—H19	120.3	C13—C12—P1	121.96 (14)
C20—C19—H19	120.3	C17—C12—P1	118.66 (14)
C21—C20—C19	120.4 (2)	C12—C13—C14	119.76 (18)
C21—C20—H20	119.8	C12—C13—H13	120.1
C19—C20—H20	119.8	C14—C13—H13	120.1
C20—C21—C22	120.4 (2)	C15—C14—C13	120.42 (19)
C20—C21—H21	119.8	C15—C14—H14	119.8
C22—C21—H21	119.8	C13—C14—H14	119.8
C21—C22—C23	120.2 (2)	C14—C15—C16	120.4 (2)
C21—C22—H22	119.9	C14—C15—H15	119.8
C23—C22—H22	119.9	C16—C15—H15	119.8
C22—C23—C18	119.5 (2)	C17—C16—C15	120.0 (2)
C22—C23—H23	120.3	C17—C16—H16	120.0
C18—C23—H23	120.3	C15—C16—H16	120.0

S4—C2—C3—S5	−2.0 (2)	C25—C26—C27—C28	0.1 (4)
S2—C2—C3—S5	−176.16 (10)	C26—C27—C28—C29	−0.6 (4)
S4—C2—C3—S3	172.12 (10)	C25—C24—C29—C28	0.5 (3)
S2—C2—C3—S3	−2.05 (18)	P1—C24—C29—C28	177.28 (16)
S1—C1—S2—C2	−179.44 (12)	C27—C28—C29—C24	0.3 (3)
S3—C1—S2—C2	0.30 (11)	C29—C24—P1—C12	151.43 (15)
C3—C2—S2—C1	1.06 (15)	C25—C24—P1—C12	−31.79 (18)
S4—C2—S2—C1	−173.51 (11)	C29—C24—P1—C6	29.86 (18)
S1—C1—S3—C3	178.55 (12)	C25—C24—P1—C6	−153.36 (16)
S2—C1—S3—C3	−1.19 (12)	C29—C24—P1—C18	−87.89 (17)
C2—C3—S3—C1	1.98 (15)	C25—C24—P1—C18	88.89 (17)
S5—C3—S3—C1	176.50 (11)	C19—C18—P1—C12	105.71 (18)
C3—C2—S4—Sn1	−28.96 (16)	C23—C18—P1—C12	−76.60 (19)
S2—C2—S4—Sn1	145.02 (9)	C19—C18—P1—C6	−132.64 (17)
C2—C3—S5—Sn1	31.82 (16)	C23—C18—P1—C6	45.04 (19)
S3—C3—S5—Sn1	−142.13 (9)	C19—C18—P1—C24	−11.5 (2)
C4ⁱ—C4—S6—Sn1	0.1 (2)	C23—C18—P1—C24	166.15 (17)
S7—C4—S6—Sn1	−179.54 (9)	C12—P1—C6—C11	−9.23 (19)
S8—C5—S7—C4	179.81 (6)	C24—P1—C6—C11	109.77 (17)
S7ⁱ—C5—S7—C4	−0.19 (6)	C18—P1—C6—C11	−131.52 (16)
C4ⁱ—C4—S7—C5	0.7 (2)	C12—P1—C6—C7	170.28 (16)
S6—C4—S7—C5	−179.65 (9)	C24—P1—C6—C7	−70.72 (18)
C4—S6—Sn1—S6ⁱ	−0.03 (6)	C18—P1—C6—C7	47.99 (18)
C4—S6—Sn1—S4	−93.91 (6)	C11—C6—C7—C8	−1.9 (3)
C4—S6—Sn1—S4ⁱ	95.55 (6)	P1—C6—C7—C8	178.63 (19)
C3—S5—Sn1—S6ⁱ	−127.73 (6)	C6—C7—C8—C9	1.6 (4)
C3—S5—Sn1—S5ⁱ	54.75 (6)	C7—C8—C9—C10	−0.4 (4)
C3—S5—Sn1—S4	−33.42 (6)	C8—C9—C10—C11	−0.6 (4)
C3—S5—Sn1—S4ⁱ	136.47 (6)	C9—C10—C11—C6	0.3 (4)
C2—S4—Sn1—S6ⁱ	121.50 (6)	C7—C6—C11—C10	0.9 (3)
C2—S4—Sn1—S6	−151.18 (6)	P1—C6—C11—C10	−179.58 (18)
C2—S4—Sn1—S5	32.81 (6)	C16—C17—C12—C13	−0.3 (3)
C2—S4—Sn1—S5ⁱ	−62.01 (6)	C16—C17—C12—P1	177.04 (19)
C2—S4—Sn1—S4ⁱ	−14.91 (6)	C6—P1—C12—C13	−111.47 (17)
C23—C18—C19—C20	−1.0 (3)	C24—P1—C12—C13	126.18 (17)
P1—C18—C19—C20	176.67 (17)	C18—P1—C12—C13	7.8 (2)
C18—C19—C20—C21	−0.1 (4)	C6—P1—C12—C17	71.25 (19)
C19—C20—C21—C22	1.3 (4)	C24—P1—C12—C17	−51.10 (19)
C20—C21—C22—C23	−1.4 (4)	C18—P1—C12—C17	−169.49 (17)
C21—C22—C23—C18	0.2 (4)	C17—C12—C13—C14	0.7 (3)
C19—C18—C23—C22	0.9 (3)	P1—C12—C13—C14	−176.60 (16)
P1—C18—C23—C22	−176.74 (19)	C12—C13—C14—C15	−0.4 (3)
C29—C24—C25—C26	−1.0 (3)	C13—C14—C15—C16	−0.2 (4)
P1—C24—C25—C26	−177.82 (17)	C12—C17—C16—C15	−0.3 (4)
C24—C25—C26—C27	0.7 (4)	C14—C15—C16—C17	0.5 (4)

Symmetry code: (i) −x+1, y, −z+1/2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C26—H26···S4ⁱ	0.93	2.69	3.598 (2)	165
C29—H29···S1ⁱⁱ	0.93	2.85	3.513 (2)	129

Symmetry codes: (i) −x+1, y, −z+1/2; (ii) −x+1, y+1, −z+1/2.

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Bis(tetra­phenyl­phospho­nium) tris­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)stannate(IV) at 293 K

Supporting information

Key indicators

checkCIF/PLATON results

Bis(tetraphenylphosphonium) tris(2-thioxo-1,3-dithiole-4,5-dithiolato)stannate(IV) at 293 K