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Acta Cryst. (2007). E63, m1135-m1137 [ doi:10.1107/S1600536807013037 ]
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-aqua-triaquabarium(II)] bis(6-methylpyridin-2-olate)]Abstract: The title compound, {[Ba(H2O)6](C6H6NO)2}n, crystallizes with polymeric chains of water-bridged Ba2+ cations having additional terminally bound water molecules, such that each ion is nine-coordinate. Ba and two independent water molecules lie on a crystallographic mirror plane. The 6-methylpyridin-2-olate anions are hydrogen bonded to the cationic chains, with both O and N atoms acting as acceptors. Further O-H
O hydrogen bonding between adjacent chains results in the formation of thick sheets parallel to the ac plane; there are no significant interactions between these sheets.
Online 28 March 2007
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