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Acta Cryst. (2007). E63, m1099-m1100  [ doi:10.1107/S1600536807011762 ]

Tris[1,2,3([eta]5)-methylcyclopentadienyl]-[mu]3-sulfido-tri-[mu]2-sulfido-tritungsten p-toluenesulfonate

K. Herbst and L. Dahlenburg

Abstract: The crystal structure of the title compound, [W3([eta]5-C6H7)3S4](C7H7SO3), consists of discrete cluster cations and organic anions. The core of the cluster cation is formed by a geometrically incomplete cubane-like W3S4 framework with one methylcyclopentadienyl ligand coordinated to each W atom.

Online 21 March 2007


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