Acta Cryst. (2007). E63, m997-m998  [ doi:10.1107/S1600536807010082 ]

-Hydrogenarsenato-²O:O'-di--oxo-⁴O:O-bis[oxo(1,10-phenanthroline-²N,N')vanadium(V)] monohydrate

S. W. Ng

Abstract: The structure refined as [H₃O]⁺·[[(C₁₂H₈N₂)V^IV(=O)O]₂(H₂AsO₄)]^- by Zheng, Zhang & Yang [J. Chem. Crystallogr. (2005). 34, 267-273] is rerefined as [V₂O₄(HAsO₄)(C₁₂H₈N₂)₂]·H₂O, whose crystal structure features a disordered [HAsO₄]^2- group that links the dinuclear molecules through O-HO hydrogen bonds into a chain running along the a axis.

Online 9 March 2007

Copyright © International Union of Crystallography
IUCr Webmaster