Acta Cryst. (2007). E63, m1226-m1227  [ doi:10.1107/S1600536807014043 ]

Aqua(5-bromidonicotinato)trimethyltin(IV)

H.-Y. Wang, H.-D. Yin and D.-Q. Wang

Abstract: The Sn atom in the title complex, [Sn(CH₃)₃(C₆H₃BrNO₂)(H₂O)], is five-coordinate with a distorted trigonal-bipyramidal geometry. The O atom of the carboxylate group occupies one of the axial sites and the O atom of the water molecule occupies the other. Water H atoms are involved in an intermolecular hydrogen-bonded network with the uncoordinated carboxylate O atom and the pyridine N atom.

Online 4 April 2007

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