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Acta Cryst. (2007). E63, m1414  [ doi:10.1107/S1600536807017497 ]

(N-tert-Butylimido)chlorido[dimethyl(1H-pyrrol-2-ylmethyl)amine-[kappa]2N,N']bis(pyridine-[kappa]N)titanium(IV) toluene solvate

D.-J. Gong, H. Wei and Y.-H. Li

Abstract: The title compound, [Ti(C4H9N)Cl(C5H5N)2(C7H11N2)]·C7H8, has a mononuclear structure featuring a six-coordinate distorted octahedral titanium(IV) centre. The central TiIV ion is coordinated by two N atoms from a dimethyl(1H-pyrrol-2-ylmethyl)amine molecule, two N atoms from two pyridine molecules, one N atom from a N-tert-butylimido ligand and one Cl atom.

Online 20 April 2007


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