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Acta Cryst. (2007). E63, m1317-m1318  [ doi:10.1107/S1600536807015905 ]

Bis{[mu]-2-[(E)-(3,5-dibromo-2-oxidophenyl)methyleneamino]ethanesulfonato-[kappa]3N,O,O':[kappa]O''}bis[methanolcopper(II)]

X.-M. Chen, S.-H. Zhang and Y. Yang

Abstract: In the centrosymmetric title compound, [Cu2(C9H7Br2NO4S)2(CH3OH)2], each CuII atom adopts a distorted square-pyramidal CuO4N coordination geometry, formed by one N atom and three O atoms from two different 2-[(E)-(3,5-dibromo-2-oxidophenyl)methyleneamino]ethanesulfonate ligands and one O atom from a methanol molecule. Adjacent CuII atoms are linked by bridging sulfonate groups to form a dinuclear compound, with a Cu...Cu distance of 5.41 (1) Å.

Online 18 April 2007


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