Acta Cryst. (2007). E63, m1540-m1541  [ doi:10.1107/S1600536807017242 ]

Dichlorido{(E)-1-[1-(pyridin-2-yl)ethylidene]thiosemicarbazonato-³N,N',S}gallium(III)

Y.-J. Fan, J.-P. Ma and Z.-X. Sun

Abstract: Reaction of GaCl₃ with E)-1-[1-(pyridin-2-yl)ethylidene]thiosemicarbazide (petc) gives the title compound, [Ga(C₈H₉N₄S)Cl₂]. The petc ligand resembles a deprotonated enol, coordinated to Ga^III through one S and two N atoms. Two Cl atoms complete a distorted trigonal-bipyramidal coordination geometry around the Ga^III atom.

Online 30 April 2007

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