Acta Cryst. (2007). E63, m1356-m1357  [ doi:10.1107/S1600536807016364 ]

Bromidobis(pyrrolidine-1-dithiocarboxylato-²S,S')antimony(III)

J. Zhai, Q.-X. Pan, H.-D. Yin, F. Li and D.-Q. Wang

Abstract: In the title compound, [SbBr(C₅H₈NS₂)₂], the Sb^III ion is coordinated by the four S atoms [Sb-S = 2.4616 (11)-2.9194 (13) Å] from two pyrrolidine-1-dithiocarboxylate ligands and a Br atom [Sb-Br = 2.8159 (7) Å] in a distorted trigonal-bipyramidal geometry. In the crystal structure, the molecules are associated into dimers with short intermolecular SbS contacts of 3.7350 (13) Å.

Online 18 April 2007

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