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Acta Cryst. (2007). E63, m1434-m1436  [ doi:10.1107/S1600536807018430 ]

([mu]2-4,4'-Bipyridyl-[kappa]2N:N')bis[bis(tri-tert-butoxysilanothiolato-[kappa]2S,O)cadmium(II)] tetrahydrofuran disolvate

A. Pladzyk, A. Dolega and K. Baranowska

Abstract: The structure of the title compound, [Cd2(C12H27O3SSi)4(C10H8N2)]·2C4H8O, consists of discrete molecules, with the two halves of the molecule related to each other by an inversion centre. Each Cd atom is coordinated by two S atoms, two O atoms and one N atom. The geometry of each Cd atom is intermediate between square-pyramidal and trigonal-bipyramidal. Two (tri-tert-butoxysilanothiolato)cadmium units are linked via one 4,4'-pyridyl ligand, forming an isolated molecule of the complex. Molecules of the tetrahydrofuran solvent are positioned above and below the plane of the 4,4'-bipyridyl.

Online 25 April 2007


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