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Acta Cryst. (2007). E63, m1223-m1225  [ doi:10.1107/S1600536807013748 ]

{2,6-Bis[(dimethylamino-[kappa]N)methyl]-4-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}phenyl-[kappa]C1}(diiodine)iodidoplatinum(II) dichloromethane hemisolvate

L. S. von Chrzanowski, M. Lutz, A. L. Spek, B. M. J. M. Suijkerbuijk and R. J. M. Klein Gebbink

Abstract: In the title compound [Pt(C17H22N3O4)I(I2)]·0.5CH2Cl2, the coordination environment of the PtII centre is distorted square-pyramidal and is defined by two neutral N atoms and an anionic C atom from the mono-anionic ligand, an iodide anion, and an additional [eta]1-coordinated I2 molecule. Intermolecular C-H...O contacts result in a dimeric structure. The asymmetric unit of (I) consists of two independent [PtI(C17H22N3O4)(I2)] molecules and a CH2Cl2 solvent molecule

Online 4 April 2007


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