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Acta Cryst. (2007). E63, m1498  [ doi:10.1107/S1600536807019769 ]

Di-[mu]-bromido-bis[([eta]4-cycloocta-1,5-diene)iridium(I)]

T. Yamagata, M. Nagata, K. Mashima and K. Tani

Abstract: The title complex, [Ir2([mu]-Br)2(C8H12)2], displays a dinuclear structure with bridging Br atoms, generated by twofold symmetry. The coordination geometry around the Ir atom is pseudo-square-planar, involving two Br atoms and two [eta]2 C=C bonds. The Ir2([mu]-Br)2 core shows a bent geometry with a hinge angle of 101.58 (3)°.

Online 25 April 2007


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