Acta Cryst. (2007). E63, m1523-m1524  [ doi:10.1107/S1600536807020545 ]

Bis(acetato-O)triaquacadmium 2-amino-4,6-dimethylpyrimidine tetrasolvate dihydrate

H. Fang and S. W. Ng

Abstract: The Cd atom (site symmetry 2) in the title compound, [Cd(C₂H₃O₂)₂(H₂O)₃]·4C₆H₉N₃·2H₂O, adopts a trigonal-bipyramidal coordination geometry but it tends towards a distorted pentagonal bipyramid owing to two long [2.674 (2) Å] CdO_COO interactions from the asymmetrically coordinated acetate anions. The neutral metal complex, uncoordinated water molecules and N-heterocycles engage in O-HO, O-HN, N-HO and N-HN hydrogen-bonding interactions, forming a three-dimensional network.

Online 30 April 2007

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