Acta Cryst. (2007). E63, m1373-m1374  [ doi:10.1107/S1600536807016492 ]

Bis(tetraethylammonium) bis[N,N'-bis(4-methylbenzothiazol-2-yl)pyridine-2,6-dicarboxamidato(2-)]nickel(II) hemihydrate

S.-G. Liu and C.-L. Ni

Abstract: In the anion of the title compound, (C₈H₂₀N)₂[Ni(C₂₃H₁₅N₅O₂S₂)₂]·0.5H₂O, the central Ni^II atom is in an octahedral environment, with four deprotonated amide N atoms in the equatorial plane and two pyridine N atoms in the axial positions. In the crystal structure, intermolecular O-HO, C-HO and C-HS hydrogen bonds link the molecules into a three-dimensional supramolecular framework.

Online 18 April 2007

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