(IUCr) Crystallography Journals Online

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Acta Cryst. (2007). E63, m1453-m1454 [ doi:10.1107/S1600536807019149 ]

Di--thiocyanato-²S:N;²N:S-bis{[N,N-dimethyl-N'-(2-pyridylmethylene-N)ethane-1,2-diamine-²N,N']nickel(II)} bis(perchlorate)

Y.-P. Diao

Abstract: In the title centrosymmetric dinuclear complex, [Ni₂(NCS)₂(C₁₀H₁₅N₃)₂](ClO₄)₂, each Ni^II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly distorted square-pyramidal coordination geometry.

Online 25 April 2007

Di--thiocyanato-2S:N;2N:S-bis{[N,N-dimethyl-N'-(2-pyridylmethylene-N)ethane-1,2-diamine-2N,N']nickel(II)} bis(perchlorate)

Y.-P. Diao

Di--thiocyanato-²S:N;²N:S-bis{[N,N-dimethyl-N'-(2-pyridylmethylene-N)ethane-1,2-diamine-²N,N']nickel(II)} bis(perchlorate)