Acta Cryst. (2007). E63, m1422-m1423  [ doi:10.1107/S1600536807017692 ]

{2,6-Dinitro-6-[(2-oxidophenyl)iminomethyl]phenolato}(ethanol)(ethanolato)oxidovanadium(V) at 100 K

J. Hartung, A. Ludwig, I. Svoboda and H. Fuess

Abstract: The central V atom of the title complex, [V(C₁₃H₇N₃O₆)(C₂H₅O)O(C₂H₆O)], is positioned within a distorted octahedral coordination polyhedron formed by five O-donor atoms and one imine N atom. An axially bound ethanol solvent molecule forms an intermolecular hydrogen bond with the iminophenolate O atom of a neighboring complex, linking molecules into centrosymmetric dimers.

Online 20 April 2007

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