Acta Cryst. (2007). E63, m1202-m1203  [ doi:10.1107/S1600536807013463 ]

(-3,5-Diphenylpyrazolato-²N:N')bis(2,2':6',2''-terpyridyl-³N)palladium(II) trinitrate

H.-P. Huang and H.-W. Ma

Abstract: In the title compound, [Pd₂(C₁₅H₂₂N₂)(C₁₅H₁₁N₃)₂](NO₃)₃, two planar Pd(terpy) units (terpy is 2,2':6',2''-terpyridyl) are bridged by a 3,5-diphenylpyrazolate ligand in an exodentate fashion, which results a clip-like cavity between the two Pd(terpy) planes. A nitrate anion is held in the cavity by an anion- interaction. The cation has crystallographic twofold rotation symmetry.

Online 4 April 2007

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