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Acta Cryst. (2007). E63, m1302-m1304  [ doi:10.1107/S1600536807015875 ]

Bis([mu]-3,5-dinitropyridin-2-olato)bis[tetraaqua(3,5-dinitropyridin-2-olato)barium(II)]

D.-D. Li, J.-B. She and G.-F. Zhang

Abstract: The barium cation in the centrosymmetric title compound, [Ba2(C5H2N3O5)4(H2O)8], is in a ten-coordinate environment with two anionic ligands and four water molecules. The Ba-O bond distances lie in the range 2.723 (2)-3.260 (2) Å. The deprotonated O atom of the ligand bridges the Ba atoms to form a dimeric unit, forming an approximately regular parallelogram Ba2O2 motif. The dimeric units are linked in a three-dimensional network by hydrogen bonds.

Online 18 April 2007


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