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Acta Cryst. (2007). E63, m1309-m1311  [ doi:10.1107/S1600536807017801 ]

[mu]-Aqua-bis([mu]-4-chlorobenzoato)bis[(4-chlorobenzoato)(1,10-phenanthroline)manganese(II)]

Y.-L. Shen, S.-L. Sun and W.-D. Song

Abstract: The title complex molecule, [Mn2(C7H4ClO2)4(C12H8N2)2(H2O)], possesses crystallographically imposed C2 symmetry. Each MnII atom is coordinated by three carboxyl O atoms from three 4-chlorobenzoate ligands, two N atoms from one 1,10-phenanthroline ligand and one bridging water molecule in a distorted octahedral coordination geometry. The Mn...Mn separation is 3.512 (3) Å. Symmetrically related dinuclear molecules form chains parallel to the c axis via [pi]-[pi] stacking interactions.

Online 18 April 2007


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